Exam 16: Aqueous Ionic Equilibrium

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A 100.0 mL sample of 0.20 mol L-1 HF is titrated with 0.10 mol L-1 KOH.Determine the pH of the solution before the addition of any KOH.The Ka of HF is 3.5 × 10-4.

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Calculate the pH of a buffer that is 0.058 mol L-1 HF and 0.058 mol L-1 LiF.The Ka for HF is 3.5 × 10-4.

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Identify the expression for the solubility product constant for BaF2.

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What happens at low pH to aluminum hydroxide precipitate?

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Identify the indicator that has two endpoints.

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Which of the following is the correct equation relating Q to Ksp for a saturated solution?

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Sodium hypochlorite,NaOCl,is the active ingredient in household bleach.What is the concentration of hypochlorite ion if 20.00 mL of bleach requires 32.00 mL of 0.500 mol L-1 HCl to reach the equivalence point?

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Solid potassium chromate (K2CrO4)is slowly added to a solution containing 0.50 mol L-1 AgNO3 and 0.50 mol L-1 Ba(NO3)2.What is the Ag+ concentration when BaCrO4 just starts to precipitate? The Ksp for Ag2CrO4 and BaCrO4 are 1.1 × 10-12 and 1.2×10101.2 \times 10 ^{- 10} \text {, } respectively.

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What is the pH of a solution prepared by mixing 25.00 mL of 0.10 mol L-1 CH3COOH with 25.00 mL of 0.010 mol L-1 CH3COONa? Assume that the volume of the solutions are additive and that Ka = 1.8 × 10-5 for CH3COOH.

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A 100.0 mL sample of 0.180 mol L-1 HClO4 is titrated with 0.270 mol L-1 NaOH.Determine the pH of the solution after the addition of 75.0 mL of NaOH.

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What is the pH of a buffer solution that is 0.251 mol L-1 in lactic acid and 0.151 mol L-1 in sodium lactate? The KaK _ { a } of lactic acid is 1.4 × 10410 ^ { - 4 } .

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A 100.0 mL sample of 0.10 mol L-1 NH3 is titrated with 0.10 mol L-1 HNO3.Determine the pH of the solution after the addition of 150.0 mL of HNO3.The Kb of NH3 is 1.8 × 10-5.

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The titration of 25.0 mL of an unknown concentration H2SO4 solution requires 83.6 mL of a 0.12 mol L-1 LiOH solution.What is the concentration of the H2SO4 solution (in mol L-1)?

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Identify a good buffer.

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You wish to prepare a buffer containing CH3COOH with a pH of 5.44.If the pKa of acetic acid is 4.74,what ratio of [CH3COO-]/[CH3COOH] must you use?

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Calculate the pH of a solution formed by mixing 200.0 mL of 0.30 mol L-1 HClO with 300.0 mL of 0.20 mol L-1 KClO.The Ka for HClO is 2.9 × 10-8.

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Determine the molar solubility of CaSO4 in a solution containing 0.100 mol L-1 Na2SO4.Ksp (CaSO4)= 2.4 × 10-5.

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If the pKa of HCOOH is 3.74 and the pH of an HCOOH/HCOONa buffer solution is 3.74,which of the following is TRUE?

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What is the molar solubility of Mg(OH)2 in a basic solution with a pH of 12.50? Ksp for Mg(OH)2 is 5.6×10125.6 \times 10 ^{- 12}

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Determine the molar solubility of BaF2 in a solution containing 0.0750 mol L-1 LiF.Ksp (BaF2)= 1.7 × 10-6.

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