Exam 16: Aqueous Ionic Equilibrium

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What is the pH of a buffer solution that is 0.295 mol L-1 in hypochlorous acid (HClO)and 0.373 mol L-1 in sodium hypochlorite (NaClO)? The KaK _ { a } of hypochlorous acid is 3.8 × 10810 ^ { - 8 } .

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A 1.00 L buffer solution is 0.250 mol L-1 in HF and 0.250 mol L-1 in LiF.Calculate the pH of the solution after the addition of 0.150 moles of solid LiOH.Assume no volume change upon the addition of the base.The Ka for HF is 3.5 × 10-4.

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A 1.00 L buffer solution is 0.150 mol L-1 in C6H5COOH and 0.250 mol L-1 in C6H5COOLi.Calculate the pH of the solution after the addition of 100.0 mL of 1.00 mol L-1 HCl.The Ka for HC7H5O2 is 6.5 × 10-5.

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A buffer solution is 0.100 mol L-1 in both C6H5COOH and C6H5COOLi and has a pH of 4.19.Which of the following pH values would you expect after the addition of a small amount of a strong base?

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What is the molar solubility of calcium hydroxide (Ca(OH)2)in water? The solubility-product constant for CaOH2 is 4.5 × 10-6 at 25C25 ^ { \circ } \mathrm { C }

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A 100.0 mL sample of 0.20 mol L-1 HF is titrated with 0.10 mol L-1 KOH.Determine the pH of the solution after the addition of 300.0 mL of KOH.The Ka of HF is 3.5 × 10-4.

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A 100.0 mL sample of 0.10 mol L-1 NH3 is titrated with 0.10 mol L-1 HNO3.Determine the pH of the solution after the addition of 200.0 mL of HNO3.The Kb of NH3 is 1.8 × 10-5.

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A 100.0 mL sample of 0.10 mol L-1 NH3 is titrated with 0.10 mol L-1 HNO3.Determine the pH of the solution before the addition of any HNO3.The Kb of NH3 is 1.8 × 10-5.

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A 100.0 mL sample of 0.10 mol L-1 Ca(OH)2 is titrated with 0.10 mol L-1 HBr.Determine the pH of the solution after the addition of 400.0 mL HBr.

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A sample contains Ba3(PO4)2, CdS,AgCl,NH4Cl,and ZnS.Identify the precipitate formed upon the addition of 6 mol L-1 HCl.

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A solution containing AgNO3 is mixed with a solution of NaCl to form a solution that is 0.10 mol L-1 in AgNO3 and 0.075 mol L-1 in NaCl.What will happen once these solutions are mixed? Ksp (AgCl)= 1.77 × 10-10.

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What is the pH at the equivalence point of a weak base-strong acid titration if 20.00 mL of NaOCl requires 28.30 mL of 0.50 mol L-1 HCl for complete neutralization? Ka = 3.0 × 10-8 for HOCl.

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The titration of 80.0 mL of an unknown concentration H3PO4 solution requires 126 mL of 0.218 mol L-1 KOH solution.What is the concentration of the H3PO4 solution (in mol L-1)?

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Calculate the pH of a solution that is 0.445 mol L-1 in sodium formate (HCOONa)and 0.265  mol L-1 \text { mol L-1 } in formic acid (HCOOH).The KaK _ { a } of formic acid is 1.77 × 10410 ^ { - 4 } .

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For a strong acid titrated with a strong base,is the equivalence point acidic,basic,or neutral?

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Consider the Ksp values for two compounds: MZ,Ksp = 1.5 × 10-20 and MZ2,Ksp = 1.5 × 10-20.Why don't these compounds have the same molar solubility?

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What is the molar solubility of silver iodide (AgI )in water? The solubility-product constant for AgI is 8.5 × 10-17 at 25 °C.

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A 1.00 L buffer solution is 0.250 mol L-1 in HF and 0.250 mol L-1 in NaF.Calculate the pH of the solution after the addition of 100.0 mL of 1.00 mol L-1 HCl.The Ka for HF is 3.5 × 10-4.

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Calculate the pH of a solution formed by mixing 100.0 mL of 0.20 mol L-1 HClO with 200.0 mL of 0.30 mol L-1 KClO.The Ka for HClO is 2.9 × 10-8.

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Which of the following compounds' solubility will not be affected by a low pH in solution?

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