Exam 16: Aqueous Ionic Equilibrium

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What is the pH of a solution prepared by mixing 50.00 mL of 0.10 mol L-1 NH3 with 5.00 mL of 0.10 mol L-1 NH4Cl? Assume that the volume of the solutions are additive and that Kb = 1.8 × 10-5 for NH3.

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What is the pH of a buffer system prepared by dissolving 10.70 grams of NH4Cl and 25.00 mL of 12 mol L-1 NH3 in enough water to make 1.000 L of solution? Kb = 1.80 × 10-5 for NH3.

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Identify the compound that is base-insoluble.

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Calculate the pH of a buffer that is 0.158 mol L-1 HClO and 0.099 mol L-1 NaClO.The Ka for HClO is 2.9 × 10-8.

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A solution contains 0.036 mol L-1 Cu2+ and 0.044 mol L-1 Fe2+.A solution containing sulfide ions is added to selectively precipitate one of the metal ions from solution.At what concentration of sulfide ion will a precipitate begin to form? What is the identity of the precipitate? Ksp(CuS)= 1.3 × 10-36,Ksp(FeS)= 6.3 × 10-18.

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A 25.0 mL sample of 0.150 mol L-1 hydrofluoric acid is titrated with a 0.150 mol L-1 NaOH solution.What is the pH before any base is added? Hydrofluoric acid is monoprotic.The KaK _ { a } of hydrofluoric acid is 3.5 × 10-4.

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What is the molar solubility of AgCl in 0.40 mol L-1 NH3? Ksp for AgCl is 1.8×10101.8 \times 10 ^{- 10} and Kf for Ag(NH3)2+ is 1.7×1071.7 \times 10^7

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A 1.0 L buffer solution is 0.050 mol L-1 CH3COOH and 0.250 mol L-1 CH3COOLi.Which of the following actions will destroy the buffer?

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For a monoprotic weak acid titrated with a strong base,is the equivalence point acidic,basic,or neutral?

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A solution containing CaCl2 is mixed with a solution of Li2C2O4 to form a solution that is 3.5 × 10-4 mol L-1 in calcium ion and 2.33 × 10-4 mol L-1 in oxalate ion.What will happen once these solutions are mixed? Ksp (CaC2O4)= 2.3 × 10-9.

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A 25.0 mL sample of 0.150 mol L-1 acetic acid is titrated with a 0.150 mol L-1 NaOH solution.What is the pH after 26.0 mL of base is added? The KaK _ { a } of acetic acid is 1.8 × 10-5.

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Determine the molar solubility of Fe(OH)2 in pure water.Ksp for Fe(OH)2 = 4.87 × 10-17.

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How many millilitres of 0.0890 mol L-1 NaOH are required to titrate 25.0 mL of 0.0680 molL1HBr\operatorname { mol } \mathrm { L } ^ { - 1 } \mathrm { HBr } to the equivalence point?

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Which of the following is the correct equation relating Q to Ksp for a supersaturated solution?

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Determine the molar solubility of AgI in pure water.Ksp (AgI)= 8.51 × 10-17.

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What is the approximate pH at the equivalence point of a weak acid-strong base titration if 25 mL of aqueous hydrofluoric acid requires 30.00 mL of 0.400 mol L-1 NaOH? Ka = 6.76 × 10-4 for HF.

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Identify the pH of normal blood.

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A 100.0 mL sample of 0.18 mol L-1 HClO4 is titrated with 0.27 mol L-1 NaOH.Determine the pH of the solution after the addition of 66.67 mL of NaOH (this is the equivalence point).

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What is the maximum ratio of conjugate base to acid in an effective buffer?

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Calculate the pH of a solution formed by mixing 250.0 mL of 0.15 mol L-1 NH4Cl with 100.0 mL of 0.20 mol L-1 NH3.The Kb for NH3 is 1.8 × 10-5.

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