Question 1

Provide the reagents necessary to carry out the following conversion.

Accepted Answer

1. (CH₃)₂CHCl /AlCl₃ 2.

Question 2

Predict the major product for the following reaction.

Accepted Answer

A)  I 
B)  II 
C)  III 
D)  IV 
E)  none of these 
A)  I 
B)  II 
C)  III 
D)  IV 
E)  none of these

Question 3

Provide the reagents necessary to carry out the following conversion.

Accepted Answer

1. Cl₂/FeCl

Question 4

Provide the structure of the major product when anisole is treated with the following reagents.
1.Br2,FeBr3
2.HNO3,H2SO4

Accepted Answer

Question 5

Which of the following reactions would produce t-butylbenzene as the major product?

Accepted Answer

A)  I 
B)  II 
C)  III 
D)  IV 
E)  all of these 
A)  I 
B)  II 
C)  III 
D)  IV 
E)  all of these

Question 6

Which of the following reactions would produce isopropylbenzene as the major product?

Accepted Answer

A)  I 
B)  II 
C)  III 
D)  IV 
E)  all of these 
A)  I 
B)  II 
C)  III 
D)  IV 
E)  all of these

Question 7

Provide a stepwise curved arrow mechanism for the chlorination of benzene in the presence of FeCl3.

Accepted Answer

@#IMG-DLM&_TB4454_00

Question 8

Predict the product for the following reaction.

Accepted Answer

The answer of Predict the product for the following reaction....

Question 9

Identify the electrophile in the chlorination of benzene.

Accepted Answer

A)  Cl2 
B)    
C)  AlCl3 
D)  AlCl2 
E)    
A)  Cl2 
B)    
C)  AlCl3 
D)  AlCl2 
E)

Question 10

Which of the following substituents will direct the incoming group to the ortho/para position during electrophilic aromatic substitution?

Accepted Answer

A)  -CH2CH3 
B)  -CF3 
C)  -OCH3 
D)  -COOCH3 
E)  both A and C 
A)  -CH2CH3 
B)  -CF3 
C)  -OCH3 
D)  -COOCH3 
E)  both A and C

Question 11

Predict the structure of the product for the following reaction.

Accepted Answer

The answer of Predict the structure of the product for...

Question 12

Predict the major product for the following reaction.

Accepted Answer

The answer of Predict the major product for the following...

Question 13

Predict the structure of the major product for the following reaction.

Accepted Answer

A)  I 
B)  II 
C)  III 
D)  IV 
E)  V 
A)  I 
B)  II 
C)  III 
D)  IV 
E)  V

Question 14

Provide the reagents necessary to carry out the following conversion.

Accepted Answer

1. fuming

Question 15

Predict the major product for the following reaction.

Accepted Answer

A)  I 
B)  II 
C)  III 
D)  IV 
E)  V 
A)  I 
B)  II 
C)  III 
D)  IV 
E)  V

Question 16

An alkyl group ___________ the benzene ring to make it __________ reactive than benzene.

Accepted Answer

The answer of An alkyl group ___________ the benzene ring...

Question 17

Provide the reagents necessary to carry out the following conversion.

Accepted Answer

1. @#IMG-DLM&_TB4454

Question 18

Propose a stepwise synthesis for the following compound from benzene.

Accepted Answer

@#IMG-DLM&_TB4454_00

Question 19

Predict the major product for the following reaction.

Accepted Answer

The answer of Predict the major product for the following...

Question 20

Predict the structure of the major product for the following reaction.

Accepted Answer

The answer of Predict the structure of the major product...

Exam 18: Aromatic Substitution Reactions

Provide the reagents necessary to carry out the following conversion.

Predict the major product for the following reaction.

Provide the reagents necessary to carry out the following conversion.

Provide the structure of the major product when anisole is treated with the following reagents. 1.Br2,FeBr3 2.HNO3,H2SO4

Which of the following reactions would produce t-butylbenzene as the major product?

Which of the following reactions would produce isopropylbenzene as the major product?

Provide a stepwise curved arrow mechanism for the chlorination of benzene in the presence of FeCl3.

Predict the product for the following reaction.

Identify the electrophile in the chlorination of benzene.

Which of the following substituents will direct the incoming group to the ortho/para position during electrophilic aromatic substitution?

Predict the structure of the product for the following reaction.

Predict the major product for the following reaction.

Predict the structure of the major product for the following reaction.

Provide the reagents necessary to carry out the following conversion.

Predict the major product for the following reaction.

An alkyl group ___________ the benzene ring to make it __________ reactive than benzene.

Provide the reagents necessary to carry out the following conversion.

Propose a stepwise synthesis for the following compound from benzene.

Predict the major product for the following reaction.

Predict the structure of the major product for the following reaction.

A Review of General Chemistry: Electrons, Bonds, and Molecular Properties

Molecular Representations

Acids and Bases

Alkanes and Cycloalkanes

Stereoisomerism

Chemical Reactivity and Mechanisms

Alkyl Halides: Nucleophilic Substitution and Elimination Reactions

Addition Reactions of Alkenes

Alkynes

Radical Reactions

Synthesis

Alcohols and Phenols

Ethers and Epoxides; Thiols and Sulfides

Infrared Spectroscopy and Mass Spectrometry

Nuclear Magnetic Resonance Spectroscopy

Conjugated Pi Systems and Pericyclic Reactions

Aromatic Compounds

Aldehydes and Ketones

Carboxylic Acids and Their Derivatives

Alpha Carbon Chemistry: Enols and Enolates

Amines

Introduction to Organometallic Compounds

Carbohydrates

Amino Acids, Peptides, and Proteins

Lipids

Synthetic Polymers

Filters

Provide the structure of the major product when anisole is treated with the following reagents. 1.Br₂,FeBr₃ 2.HNO₃,H₂SO₄

Provide a stepwise curved arrow mechanism for the chlorination of benzene in the presence of FeCl₃.

An alkyl group _ the benzene ring to make it reactive than benzene.