Exam 37: Molecules

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The characteristic energy of rotation E0r for the O2 molecule is 1.78 ×\times 10-4 eV.Calculate the frequency of the photon absorbed for the excitation from the l = 3 to l = 4 rotational level of this diatomic molecule.

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Transitions between vibrational states of different electronic states result in the emission of photons in or near the _______ portion of the electromagnetic spectrum.

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The energies due to the electronic excitations of a molecule are of the order of 1 eV,whereas

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When a NaCl molecule is formed from neutral Na and Cl atoms,

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Gases such as CO2 and methane are considered greenhouse gases.This is because

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Which of the following statements about covalent bonding is true?

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The energy released by an atom's acquisition of one electron is called its

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The effective force constant of the CO molecule is 1.86 kN/m.With 12 u for the mass of the carbon atom and 16 u for the mass of the oxygen atom,the frequency of vibration of the CO molecule is

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The dissociation energy of an ionic compound is the negative of the potential energy of the positive-negative ion system when the ions are

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If the electrostatic potential energy of Na+ and F- ions at their equilibrium separation (with U = 0 at infinite separation)is -1.19 ×\times 10-18 J,then their equilibrium separation must be approximately

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The _______ bond is responsible for the bonding of identical or similar atoms.

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The reduced mass of a two-body system in which the masses of the bodies are 2 u and 5 u is

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The magnetron of a microwave oven generates a frequency of 2.45 GHz.This frequency corresponds to the first vibrational level, The magnetron of a microwave oven generates a frequency of 2.45 GHz.This frequency corresponds to the first vibrational level,   ,of a water molecule.Assuming that the energy is given by   ,the moment of inertia of the water molecule is ,of a water molecule.Assuming that the energy is given by The magnetron of a microwave oven generates a frequency of 2.45 GHz.This frequency corresponds to the first vibrational level,   ,of a water molecule.Assuming that the energy is given by   ,the moment of inertia of the water molecule is ,the moment of inertia of the water molecule is

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In the absorption spectrum of the diatomic molecule HCl the central frequency is at 8.67 ×\times 1013 Hz,while the absorption peaks on either side are separated by 5.9 ×\times 1011 Hz.What is the energy of the lowest vibrational state?

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Which one of the following statements is true of the van der Waals bond?

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The reduced mass of a two-body system is 2.1 u.If one of the masses is 3 u,then what is the mass of the second body?

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In the absorption spectrum of the diatomic molecule HCl the central frequency is at 8.67 ×\times 1013 Hz,while the absorption peaks on either side are separated by 5.9 ×\times 1011 Hz.What is the average moment of inertia of a rotating HCl molecule?

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If the H2 molecule has a rotational energy of E0r = 0.040 MeV,what is the average distance between the two atoms?

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From the frequency of vibration the effective force constant of the HCl molecule is found to be 840 N/m.In order to appreciate the stiffness of the binding force,or imaginary "spring," between the H and Cl,calculate how far a spring of the same stiffness would extend if a 10 kg weight were hung from it.

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