Exam 15: Complex Ion and Precipitation Equilibria

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Consider the reaction Cu(OH)2(s)+ 4NH3(aq) ? Cu(NH3)42+(aq)+ 2OH?(aq) K = 4 × 10?7 If the Kf for Cu(NH3)42+ is 1 × 1012,what is the value of Ksp for Cu(OH)2?

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The formation constant for Ag(CN)2−(aq)is 2 × 1020.At what cyanide ion concentration is [Ag+] = [ Ag(CN)2−]?

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What is the water solubility of BaF2(s)in 0.033 M KF(aq)at 25°C? The Ksp of BaF2 is 1.8 × 10-7 at 25°C.

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The Ksp of calcium iodate is 7.1 × 10−7.What is the concentration of Ca2+ in equilibrium with Ca(IO3)2(s)if [IO3−] = 3.3 × 10−2 M?

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A saturated solution of lead(II)sulfate can be prepared by diluting 0.0101 g of PbSO4 to 250 mL.What is the Ksp of lead(II)sulfate?

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What is the net ionic equation for the reaction of KCl with a strong base?

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The solubility of BaCrO4(s)in water is 3.7 milligrams in 1.0 L at 25°C.What is the value of Ksp for BaCrO4?

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What volume of water is needed to completely dissolve 1.0 g of Ag2CrO4 (Ksp = 8.0 × 10−12,MM = 331.8 g/mol)?

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What is the water solubility of PbI2 (Ksp = 8.4 × 10−9,MM = 461 g/mol)in moles per liter?

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What is the concentration of Ag+ in a saturated solution of Ag2CrO4 if Ksp = 1 × 10−12?

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For AgCl,Ksp = 1.8 × 10−10.What will occur if 250 mL of 1.5 × 10−3 M NaCl is mixed with 250 mL of 2.0 × 10−7M AgNO3?

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The Ksp of BaSO4 is 1.1 × 10-10 at 25°C.What mass of BaSO4 (molar mass = 233.4 g/mol)will dissolve in 1.0 L of water at 25°C?

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Consider the equilibrium of Ca(OH)2(s)in water. Ca(OH)2(s) ? Ca2+(aq)+ 2OH?(aq), What is the effect of raising the pH of the solution?

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The Ksp of Fe(OH)3(s)is 3 × 10−39.What concentration of Fe3+ can exist in solution at pH 3.0?

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What is the chemical equation that describes the dissolution of calcium iodate in water?

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Which of the following equations is the solubility product of Cu(II)hydroxide,Cu(OH)2?

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The Ksp of aluminum hydroxide,Al(OH)3,is 2 × 10−31.What pH is required to limit the Al3+ concentration to less than or equal to 1 × 10−10 M?

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For Mg(OH)2,Ksp = 6 × 10−12.What will occur if 1.0 L of 0.010 M Mg(NO3)2 is prepared at pH 10.00?

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Which of the boxes below represents solid MX2 in equilibrium with M2+ (squares)and X− (circles)?

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A solution containing an unknown metal ion is analyzed by qualitative analysis.Addition of chloride has no effect on the solution.Addition of H2S at pH 0.5 results in a precipitate.What group of cations is present?

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