Exam 15: Complex Ion and Precipitation Equilibria

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An aqueous solution contains 0.010 M Br- and 0.010 M I-.If Ag+ is added until AgBr(s)just begins to precipitate,what are the concentrations of Ag+ and I-? (Ksp of AgBr = 5.4 × 10-13,Ksp of AgI = 8.5 × 10-17)

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What is the net ionic equation for the reaction of ZnS with a strong acid?

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What is the equilibrium constant expression for the dissolution of solid lead oxalate,PbC2O4,in water?

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Which of the following metals will precipitate as chloride salts: Ag+,Pb2+,Ca2+,K+,and Cu2+?

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For Ca(OH)2,Ksp = 4.0 × 10−6.What will occur if 1.0 L of 0.100 M Ca(NO3)2 is prepared in a solution that is buffered at pH 12.50?

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The Ksp of BaSO4 is 1.1 × 10-10 at 25°C.What mass of BaSO4 (molar mass = 233.4 g/mol)will dissolve in 1.0 L of water at 25°C?

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For PbCl2,Ksp = 1.7 × 10−5.What will occur if 250 mL of 0.12 M Pb(NO3)2 is mixed with 250 mL of 0.070 M NaCl?

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The Ksp of calcium phosphate is 1 × 10−33.What is the concentration of Ca2+ in equilibrium with Ca3(PO4)2(s)if [PO43] = 1 × 10−5 M?

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In the qualitative analysis scheme,Mg2+ is a group IV cation.What anion is used to precipitate Mg2+?

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What is the water solubility of Hg2Br2 (Ksp = 6 × 10−23)in moles per liter?

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What is the net ionic equation for the reaction of an aqueous solution of AgNO3 and NH3?

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What is the net ionic equation for the reaction of Ca3(PO4)2 with a strong acid?

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What is the water solubility of AgCl (Ksp = 1.8 × 10−10,MM = 143.4 g/mol)in grams per liter?

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What is the water solubility of AgCl (Ksp = 1.8 × 10−10)in 0.25 M NaCl?

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What is the water solubility of AgI (Ksp = 1 × 10−16,MM = 234.8 g/mol)in moles per liter?

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Consider the equilibrium of magnesium fluoride,MgF2(s),in water. MgF2(s) ? Mg2+(aq)+ 2F?(aq), What is the effect of adding perchloric acid (i.e.decreasing the pH of solution)?

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Which of the following equations represents the formation constant of Ti(NH3)63+?

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A solution contains 0.10 M Ca2+ and 0.10 M Mg2+.The pH of the solution is raised without changing the volume of the solution.What percentage of Mg2+ remains in solution when Ca(OH)2(s)first begins to precipitate? (Ksp of Ca(OH)2 = 4.0 × 10−6 and Ksp of Mg(OH)2 = 7.1 × 10−12)

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Determine the equilibrium constant,K,for the following reaction, Ca(OH)2(s)+ 2H+(aq)→ Ca2+(aq)+ 2H2O(l) Given the Ksp of Ca(OH)2 is 4.0 × 10−6 and Kw is 1.0 × 10−-14.

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