Exam 9: Liquids and Solids

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Iron packs in a body-centered cubic structure.If an iron atom has a radius of 126 pm,what is the distance between lattice points at two opposite corners of the unit cell? (Note: a line drawn between the points would go through the center of the unit cell)

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D

In which of the following pure solids is it necessary to break covalent bonds in order to make a liquid or gas?

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E

What is the correct method for determining the number of atoms in a face-centered cubic cell?

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D

Carbon tetrachloride,an organic solvent,has a molar heat of vaporization of 29.82 kJ/mol.If CCl4 has a normal boiling point of 3.50 × 102 K,what is its vapor pressure at 273 K? (R = 8.31 J/mol⋅K)

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What is a correct method for determining the number of atoms in a body-centered cubic cell?

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The normal boiling point of a liquid is

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Arrange Cl2,ICl,and Br2 in order from lowest to highest melting point.

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For a simple cubic unit cell,what percentage of the space in the cell is occupied by the atoms at the corners of the cell?

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Sulfur dioxide has a vapor pressure of 462.7 mm Hg at -21.0°C and a vapor pressure of 140.5 mm Hg at -44.0°C.What is the molar heat of vaporization of sulfur dioxide? (R = 8.31 J/K⋅mol)

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Which of the following nonpolar molecules has the highest boiling point?

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Use the phase digram to answer the following questions: Use the phase digram to answer the following questions:   -According to the phase diagram ,which point corresponds to conditions where only the solid phase exists? -According to the phase diagram ,which point corresponds to conditions where only the solid phase exists?

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All of the following statements are correct EXCEPT

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Sulfur dioxide has an enthalpy of vaporization of 24.9 kJ/mol.At 205 K,SO2 has a vapor pressure of 30.3 mm Hg.What is the normal boiling point temperature of SO2? (R = 8.31 J/K.mol)

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Naphthalene,a substance present in some mothballs,has a molar heat of vaporization of 49.4 kJ/mol.If the vapor pressure of naphthalene is 0.300 mm Hg at 298 K,what is the temperature at which the vapor pressure is 7.60 × 102 mm Hg? (R = 8.31 J/K.mol)

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Xenon has a molar heat of vaporization of 12.6 kJ/mol and a vapor pressure of 1.00 atm at -108.0°C.What is the vapor pressure of xenon at -148.0°C? (R = 8.31 J/K.mol)

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All of the following statements are incorrect EXCEPT

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What type of solid is generally soluble in nonpolar solvents?

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Arrange the noble gases in order from weakest to strongest interatomic forces.

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Potassium crystallizes in a body-centered cubic unit cell.If the length of an edge of the unit cell is 524 pm,what is the atomic radius (in pm)of a potassium atom?

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If a pure substance begins at point A on the phase diagram below and the pressure on the substance is reduced at constant temperature until point B is reached,what process occurs? If a pure substance begins at point A on the phase diagram below and the pressure on the substance is reduced at constant temperature until point B is reached,what process occurs?

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