Exam 17: Principles of Chemical Reactivity: the Chemistry of Acids and Bases

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The complete reaction of an acid and base is as follows. HNO3(aq) + LiOH(aq) ? H2O( \ell ) + LiNO3(aq) What is the equilibrium constant for the net ionic reaction at 25 °C?

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Which of the following species cannot act as a Lewis base?

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Consider the Ka values for the following acids: Cyanic acid, HOCN, 3.5 × 10-4 Formic acid, HCHO2, 1.7 × 10-4 Lactic acid, HC3H5O3, 1.3 × 10-4 Propionic acid, HC3H5O2, 1.3 × 10-5 Benzoic acid, HC7H5O2, 6.3 × 10-5 Given initially equimolar solutions of each weak acid, which solution will have the highest pH once equilibrium is established?

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What is the hydroxide-ion concentration of a 0.190 M sodium oxalate (Na2C2O4) solution? For oxalic acid (H2C2O4), Ka1 = 5.6 × 10-2 and Ka2 = 5.1 × 10-5. (Kw = 1.01 × 10-14)

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What is the pH of the solution that results from mixing 75 mL of 0.50 M NH3(aq) and 75 mL of 0.50 HCl(aq) at 25 °C? (Kb for NH3 = 1.8 × 10-5)

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The equilibrium constant, Ka,for a monoprotic acid (benzoic acid) is 6.3 × 10-5. Which of the following is the correct value of Kb for the benzoate ion, the conjugate base of benzoic acid?

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According to the Brønsted-Lowry definition, a base

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The H3O+ concentration of a solution is 5.9 × 10-6 M. What is the pH of the solution?

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Which of the following does not behave as an amphiprotic species in water?

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What is the equilibrium pH of an initially 0.83 M solution of the monoprotic acid 3-chloropropanoic acid at 25°C (Ka = 7.8×1057.8 \times 10 ^ { - 5 } )?

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Which of the following statements is/are consistent with the Brønsted-Lowry concept of acids and bases? 1.A conjugate acid–base pair consists of two species that may differ by one proton. 2. A Brønsted–Lowry base is defined as a hydroxide ion donor. 3.Brønsted–Lowry acid-base reactions are restricted to only aqueous solutions.

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A molecule that can behave as either a Brønsted-Lowry acid or base is termed ________.

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Which of the following species is the strongest acid in an aqueous solution?

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The pH of a solution at 25 °C in which [OH-] = 3.9 × 10-5 M is _____. (Kw = 1.01 × 10-14)

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A Brønsted-Lowry base is defined as a hydroxide ion donor.

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A 0.10 M solution of a weak monoprotic acid has a hydronium-ion concentration of 8.0 × 10-4 M. What is the acid-ionization constant, Ka, for this acid?

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Which acid-base reaction results in acidic solution?

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Calculate the pH of a 0.09 M solution of ascorbic acid (Ka1 = 7.9 × 10-5; Ka2 is 1.6 × 10-12).

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The pH of aqueous 0.10 M pyridine (C5H5N) ion is 9.09. What is the Kb of this base?

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A conjugate acid-base pair consists of two species that may differ by one proton.

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