Exam 17: Principles of Chemical Reactivity: the Chemistry of Acids and Bases

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What is the equilibrium constant for the following reaction, HCO2H(aq) + CN-(aq) \rightleftharpoons HCO2-(aq) + HCN(aq) And does the reaction favor the formation of reactants or products? The acid dissociation constant, Ka, for HCO2H is 1.8 × 10-4 and the acid dissociation constant for HCN is 4.0 × 10-10.

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Consider the Ka values for the following acids: Cyanic acid, HOCN, 3.5 × 10-4 Formic acid, HCHO2, 1.7 × 10-4 Lactic acid, HC3H5O3, 1.3 × 10-4 Propionic acid, HC3H5O2, 1.3 × 10-5 Benzoic acid, HC7H5O2, 6.3 × 10-5 Which of the following is the strongest acid?

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Hydrofluoric acid has a pKa value of 3.14. What is the value of pKb for fluoride ion?

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Which of the following statements about the reaction below is correct? HCO3-(aq) + H2O( \ell ) \rightleftharpoons CO32-(aq) + H3O+(aq)

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H3PO3 is a diprotic weak acid. What is the balanced equilibrium defined as Kb2 of H3PO3?

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Which of the following substances is never a Brønsted-Lowry acid in an aqueous solution?

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When a Lewis acid combines with a Lewis base, the base supplies both the electrons to the bond. This type of chemical bond is called a(n) _____ covalent bond.

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What is the hydroxide-ion concentration in a solution formed by combining 200. mL of 0.15 M HCl with 300. mL of 0.090 M NaOH at 25°C? HCl(aq) + NaOH(aq) → NaCl(aq) + H2O(l)

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Which of the following is the correct hydronium ion ,H3O+,concentration of 0.0013 M KOH(aq) at 25 °C? (Kw = 1.01 × 10-14)

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What is the OH- concentration of an aqueous solution with a pH of 9.83? (Kw = 1.01 × 10-14)

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A solution has a hydroxide ion concentration of 0.0040 M. Calculate the pOH of the solution at 25 °C. (Kw = 1.01 × 10-14)

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Which of the following equations shows that isoquinoline, C9H7N, behaves as a Brønsted-Lowry base in water?

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Which equation depicts the hydrogen phosphate ion behaving as a Brønsted-Lowry base in water?

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Which of the following is the correct hydroxide ion concentration in 0.48 M CH3CO2-(aq)? (Kb of CH3CO2- = 5.6 × 10-10)

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Carbonic acid is a diprotic acid, H2CO3, with Ka1 = 4.2 × 10-7 and Ka2 = 4.8 × 10-11 at 25°C. The ion product for water is Kw = 1.0 × 10-14 at 25°C. What is the OH- concentration of a solution that is 0.39 M in Na2CO3?

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What is the H3O+ concentration in 0.0055 M Ba(OH)2(aq) at 25 °C? (Kw = 1.01 × 10-14)?

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Which of the following expressions is not equivalent to the formula of pH?

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What is Ka at 25°C for the following equilibrium given Kb (CH3NH2) = 4.4 × 10-4 at 25°C.? CH3NH3+(aq) + H2O(l) \rightleftharpoons CH3NH2(aq) + H3O+(aq)

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When a Lewis acid and a Lewis base combine, the product may be referred to as an acid-base ________.

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At 50°C the autoionization constant for pure water, Kw, is 5.48×10145.48 \times 10 ^ { - 14 } . What is the H3O+ concentration in pure water at 50°C?

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