Exam 17: Principles of Chemical Reactivity: the Chemistry of Acids and Bases

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What is the hydroxide-ion concentration in a 0.10 M solution of Na2CO3? For carbonic acid, Ka1 = 4.2 × 10-7 and Ka2 = 4.8 × 10-11. (Kw = 1.0 × 10-14)

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Identify from the following list of molecules and ions which behave as Lewis acids: CO2, NH3, BCl3, and Fe3+.

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Given that Ka for the weak acid HA is 3.49 × 10-8, calculate K for the reaction of HA with OH-. HA(aq) + OH?(aq) D A?(aq) + H2O( \ell )

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Which of the following substances is never a Brønsted-Lowry base in an aqueous solution?

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What is the pH of the solution which results from mixing 50.0 mL of 0.30 M HF(aq) and 50.0 mL of 0.30 M NaOH(aq) at 25 °C? (Ka of HF = 7.2 × 10-4)

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What is the conjugate base of [Fe(H2O)6]3+(aq)?

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What volume of water must be added to 14.4 mL of a pH 2.0 solution of HNO3 in order to change the pH to 4.0?

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What is the hydronium-ion concentration of a 0.25 M solution of HCN (Ka = 4.9 × 10-10) at 25°C?

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Arrange the following acids in order of decreasing acid strength in aqueous solution: HBr, HOCl, HOBr, and HOI.

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Aqueous solutions of ammonia (NH3) and hydrogen cyanide (HCN) react to produce ammonium cyanide, (NH4CN) according to the following equilibrium reaction. NH3(aq) + HCN(aq) D NH4+(aq) + CN?(aq) Given the following equilibrium constants, which statement best describes the reaction once equilibrium is established? (Kw = 1.01 × 10-14) =5.6\times1 =4.0\times1

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What is the pH of a solution prepared by dissolving 0.459 L of HCl(g), measured at STP, in enough water such that the total volume of the solution is 5.50 L? (R = 0.0821 L · atm/K·mol)

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The autoionization of pure water, as represented by the equation below, is known to be endothermic (?r? > 0). Which of the following correctly states what occurs as the temperature of pure water is raised? H2O(l) + H2O(l) \rightleftharpoons H3O+(aq) + OH-(aq) ?r? > 0

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Which of the following ionic compounds does not produce a basic aqueous solution at 25 °C?

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The concentration of H3O+ in a solution is 5 × 10-4 M at 25°C. What is its hydroxide-ion concentration? (Kw = 1.01 × 10-14)

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What is the pH of a 0.33 M solution of methylamine (CH3NH2, Kb = 4.4 × 10-4) at 25oC? (Kw = 1.01 × 10-14)

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What is the equilibrium hydronium ion concentration of an initially 4.5 M solution of hypoiodous acid, HOI, at 25°C (Ka = 2.3×10112.3 \times 10 ^ { - 11 } )?

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At 25 °C, all of the following ions produce an acidic solution, except ____.

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Calculate the pH of a 1.7 M solution of H2A (Ka1 = 1.0 × 10-6 and Ka2 is 1.0 × 10-10).

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The chemical equations below show the reaction of Al(OH)3 as a Lewis acid and as a Lewis base, respectively. Al(OH)3(s) + OH-(aq) \rightleftharpoons Al(OH)4-(aq) Al(OH)3(s) + 3 H3O+(aq) \rightleftharpoons Al3+(aq) + 3 H2O( \ell ) Substances that can behave as either Lewis acids or bases are called ________ substances.

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An aqueous solution with a pH of 10.60 is diluted from 1.0 L to 2.0 L. What is the pH of the diluted solution?

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