Exam 6: Principles of Chemical Reactivity: Energy and Chemical Reactions

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A bomb calorimeter has a heat capacity of 2.47 kJ/K. When a 0.103-g sample of a certain hydrocarbon was burned in this calorimeter, the temperature increased by 2.14 K. Calculate the energy of combustion for 1 g of the hydrocarbon.

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How much energy is gained by copper when 68.4 g of copper is warmed from 13.4 °C to 78.4 °C? The specific heat capacity of copper is 0.385 J/(g·°C).

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One statement of the first law of thermodynamics is that

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_____ is used to measure the energy evolved or absorbed as heat in a chemical or physical process.

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Specific heat capacity is

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Heat capacity is defined as

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Which of these physical changes would require the release of energy?

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A 170.0-g sample of metal at 83.00°C is added to 170.0 g of H2O(l) at 15.00°C in an insulated container. The temperature rises to 18.16°C. Neglecting the heat capacity of the container, what is the specific heat capacity of the metal? The specific heat capacity of H2O(l) is 4.18 J/(g·°C).

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What is ?rH° for the following phase change? LiF(s) ? LiF(l) Substance ΔHf( kJ/molrxn)\quad \Delta H ^ { \circ } {}_f ( \mathrm {~kJ} / \mathrm { mol } - \mathrm { rxn } ) LiF(s)616.93\operatorname { LiF } ( s ) \quad - 616.93 LiF(l)598.65\operatorname { LiF } ( l ) \quad - 598.65

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Hydrazine, N2H4, is a liquid used as a rocket fuel. It reacts with oxygen to yield nitrogen gas and water. N2H4( \ell ) + O2(g) ? N2(g) + 2 H2O( \ell ) The reaction of 6.50 g N2H4 evolves 126.2 kJ of heat. Calculate the enthalpy change per mole of hydrazine combusted.

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Determine the standard enthalpy of formation of Fe2O3(s) given the thermochemical equations below. Fe(s) + 3 H2O( \ell ) ? Fe(OH)3(s) + 3/2 H2(g) ?rH° = +160.9 kJ/mol-rxn H2(g) + 1/2 O2(g) ? H2O( \ell ) ?rH° = -285.8 kJ/mol-rxn Fe2O3(s) + 3 H2O( \ell ) ? 2 Fe(OH)3(s) ?rH° = +288.6 kJ/mol-rxn

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In thermodynamics, a(n) ________ is defined as the object, or collection of objects, being studied. The surroundings include everything else.

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Combustion of 2.14 g of liquid benzene (C6H6) causes a temperature rise of 16.2 °C in a constant-pressure calorimeter that has a heat capacity of 5.53 kJ/°C. What is ?H for the following reaction? C6H6(l) + 152\frac { 15 } { 2 } O2(g) ? 6 CO2(g) + 3 H2O( \ell )

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Calculate ΔU of a gas for a process in which the gas absorbs 45 J of heat and does 11 J of work by expanding.

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Many homes are heated using natural gas. The combustion of natural gas converts

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It is relatively easy to change the temperature of a substance that

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Which one of the following statements is INCORRECT?

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Which of the following chemical equations does not correspond to a standard molar enthalpy of formation?

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What is the change in internal energy of the system (ΔU) if 65 kJ of heat energy is evolved by the system and 62 kJ of work is done on the system for a certain process?

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The following reaction of iron oxide with aluminum is an exothermic reaction. Fe2O3(s) + 2 Al(s) → 2 Fe(s) + Al2O3(s) The reaction of 5.00 g of Fe2O3 with excess Al(s) evolves 26.6 kJ of energy in the form of heat. Calculate the enthalpy change per mole of Fe2O3.

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