Exam 6: Principles of Chemical Reactivity: Energy and Chemical Reactions

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When 1 mole of Fe2O3(s) reacts with H2(g) to form Fe(s) and H2O(g) by the following reaction, 98.8 kJ of energy is absorbed. Fe2O3(s) + 3 H2(g) → 2 Fe(s) + 3 H2O(g) When 1 mole of Fe<sub>2</sub>O<sub>3</sub>(s) reacts with H<sub>2</sub>(g) to form Fe(s) and H<sub>2</sub>O(g) by the following reaction, 98.8 kJ of energy is absorbed.  Fe<sub>2</sub>O<sub>3</sub>(s) + 3 H<sub>2</sub>(g) → 2 Fe(s) + 3 H<sub>2</sub>O(g)   (A)    (B) Is the reaction endothermic or exothermic, and which of the enthalpy diagrams above Represents this reaction? (A) When 1 mole of Fe<sub>2</sub>O<sub>3</sub>(s) reacts with H<sub>2</sub>(g) to form Fe(s) and H<sub>2</sub>O(g) by the following reaction, 98.8 kJ of energy is absorbed.  Fe<sub>2</sub>O<sub>3</sub>(s) + 3 H<sub>2</sub>(g) → 2 Fe(s) + 3 H<sub>2</sub>O(g)   (A)    (B) Is the reaction endothermic or exothermic, and which of the enthalpy diagrams above Represents this reaction? (B) Is the reaction endothermic or exothermic, and which of the enthalpy diagrams above Represents this reaction?

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Determine the heat of evaporation of carbon disulfide, CS2( \ell ) ? CS2(g) Given the enthalpies of reaction below. C(s) + 2 S(s) ? CS2( \ell ) ?rH° = +89.4 kJ/mol-rxn C(s) + 2 S(s) ? CS2(g) ?rH° = +116.7 kJ/mol-rxn

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Determine the standard enthalpy of formation of calcium carbonate from the thermochemical equations given below. (()\rightarrow()+(\ell) =65.2/- (()+()\rightarrow()+(\ell) =-113.8/- ()+()\rightarrow() =-393.5/- 2()+()\rightarrow2() =-1270.2/-

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Given the thermochemical equation 4AlCl3(s) + 3O2(g) ? 2Al2O3(s) + 6Cl2(g); ?rH = -529 kJ/mol-rxn Find ?rH For the following reaction. 13\frac { 1 } { 3 } Al2O3(s) + Cl2(g) ? 23\frac{2}{3} AlCl3(s) + 12\frac { 1 } { 2 } O2(g)

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CaO(s) reacts with water to form Ca(OH)2(aq). If 6.50 g CaO is combined with 99.70 g H2O in a coffee cup calorimeter, the temperature of the resulting solution increases from 21.7 °C to 43.1 °C. Calculate the enthalpy change for the reaction per mole of CaO. Assume that the specific heat capacity of the solution is 4.18 J/g⋅K.

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Calculate the energy in the form of heat (in kJ) required to convert 325 grams of liquid water at 20.0 °C to steam at 115 °C. Assume that no energy in the form of heat is transferred to the environment. (Heat of fusion = 333 J/g; heat of vaporization = 2256 J/g; specific heat capacities: liquid water = 4.184 J/g⋅K, steam = 1.92 J/g⋅K)

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What quantity, in moles, of hydrogen is consumed when 179.6 kJ of energy is evolved from the combustion of a mixture of H2(g) and O2(g)? H2(g) + 12\frac { 1 } { 2 } O2(g) ? H2O(l); ?rH° = -285.8 kJ/mol-rxn

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How much heat is liberated at constant pressure if 0.515 g of calcium carbonate reacts with 32.7 mL of 0.498 M hydrochloric acid? CaCO3(s) + 2HCl(aq) → CaCl2(aq) + H2O(l) + CO2(g); ΔrH° = -15.2 kJ/mol-rxn

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A chemical reaction in a bomb calorimeter evolves 3.86 kJ of energy in the form of heat. If the temperature of the bomb calorimeter increases by 4.17 K, what is the heat capacity of the calorimeter?

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Which of the following has zero standard enthalpy of formation at 25 °C?

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Which of the following reactions corresponds to the thermochemical equation for the standard molar enthalpy of formation of solid zinc nitrate?

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If 35.0 g H2O at 22.7 °C is combined with 65.0 g H2O at 87.5 °C, what is the final temperature of the mixture? The specific heat capacity of water is 4.184 J/g⋅K.

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Using the following thermochemical data: 2(s)+6(g)\rightarrow2(s)+3(g) =-1929.4/ mol-rxn 2(s)+6(g)\rightarrow2(s)+3(g) =-1498.0/- Calculate ?rH° for the following reaction: SmF3(s) + 3HCl(g) ? SmCl3(s) + 3HF(g)

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The heat of vaporization of benzene, C6H6, is 30.7 kJ/mol at its boiling point of 80.1 °C. How much energy in the form of heat is required to vaporize 102 g benzene at its boiling point?

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What is the standard enthalpy of formation of CaCO3(s)+ CaO(s) + CO2(g) ? CaCO3(s); ?H° = -179.4 kJ/mol-rxn Substance (/ mol-rxn ) (s) -634.9 (g) -393.5

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What is the minimum mass of ice at 0.0 °C that must be added to 1.00 kg of water to cool the water from 28.0 °C to 12.0 °C? (Heat of fusion = 333 J/g; specific heat capacities: ice = 2.06 J/g⋅K, liquid water = 4.184 J/g⋅K)

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Calculate the energy in the form of heat (in kJ) required to change 76.9 g of liquid water at 25.2 °C to ice at -15.2 °C. Assume that no energy in the form of heat is transferred to the environment. (Heat of fusion = 333 J/g; heat of vaporization = 2256 J/g; specific heat capacities: ice = 2.06 J/g⋅K, liquid water = 4.184 J/g⋅K)

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According to the reaction given below, the standard enthalpy change for the combustion of 1 mole of propane is -2043.0 kJ. C3H8(g) + 5 O2(g) ? 3 CO2(g) + 4 H2O(g) Calculate ?fH° for propane based on the given standard molar enthalpies of formation. molecule \Delta(/ mol-rxn ) () -393.5 () -241.8

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If 50.0 g of benzene (C6H6) absorbs 2.71 kJ of energy in the form of heat at 25.0 °C, what is the final temperature of benzene? The specific heat capacity of benzene is 1.72 J/g ⋅ K.

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Exactly 149.6 J will raise the temperature of 10.0 g of a metal from 25.0 °C to 60.0 °C. What is the specific heat capacity of the metal?

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