Exam 6: Principles of Chemical Reactivity: Energy and Chemical Reactions

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Acetylene, C2H2, is a gas used in welding. The molar enthalpy of combustion for acetylene is -2599 kJ. A mass of 0.338 g C2H2(g) is combusted in a bomb calorimeter. If the heat capacity of the calorimeter is 729 J/K and it contains 1.150 kg of water, what is the temperature increase of the bomb calorimeter? The specific heat capacity of water is 4.184 J/g⋅K and the molar mass of acetylene is 26.04 g/mol.

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If 46.1 g of copper at 11.6 °C is placed in 85.0 g of water at 72.4 °C, what is the final temperature of the mixture? The specific heat capacities of copper and water are 0.385 J/g ⋅ K and 4.184 J/g ⋅ K, respectively.

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When 50.0 mL of 1.60 M of HCl(aq) is combined with 50.0 mL of 1.70 M of NaOH(aq) in a coffee-cup calorimeter, the temperature of the solution increases by 10.7°C. What is the change in enthalpy for this balanced reaction? HCl(aq) + NaOH(aq) ? NaCl(aq) + H2O( \ell ) Assume that the solution density is 1.00 g/mL and the specific heat capacity of the solution is 4.18 J/g?°C.

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Determine ?rH° for the following reaction, 2 NH3(g) + 5/2 O2(g) ? 2 NO(g) + 3 H2O(g). The thermochemical equations for the reaction are given below: ()+()\rightarrow2() =+180.8/ mol-rxn ()+3()\rightarrow2() =-91.8/- 2()+()\rightarrow2() =-483.6/-

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When 10.0 g of KOH is dissolved in 100.0 g of water in a coffee-cup calorimeter, the temperature rises from 25.18 °C to 47.53 °C. What is the enthalpy change per gram of KOH dissolved in the water? Assume that the solution has a specific heat capacity of 4.18 J/g ⋅ K.

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The thermochemical equation for the combustion of methanol is given below. CH3OH( \ell ) + 3/2 O2(g) ? CO2(g) + 2 H 2O(g) ?rH° = -638.7 kJ/mol-rxn What is the enthalpy change for the combustion of 8.59 g of CH3OH?

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Which of the following thermodynamic quantities are state functions: heat (q), work (w), enthalpy change (ΔH), and/or internal energy change (ΔU)?

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44.0 g of ice at -20.0 °C is mixed with 325 g of water at 32.1 °C. Calculate the final temperature of the mixture. Assume that no energy in the form of heat is transferred to the environment. (Heat of fusion = 333 J/g; specific heat capacities: ice = 2.06 J/g⋅K, liquid water = 4.184 J/g⋅K)

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What is the overall chemical equation that results from the sum of the given steps? ​ 2 C(s) + 2 H2O(g) → 2 CO(g) + 2 H2(g) CO(g) + H2O(g) → CO2(g) + H2(g) CO(g) + 3 H2(g) → CH4(g) + H2O(g) ​

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