Exam 19: Ionic Equilibria in Aqueous Systems

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You need to use KH2PO4 and K2HPO4 to prepare a buffer with a pH of 7.45. Which of the following ratios of [base]/[acid] is required? For phosphoric acid, (H3PO4), Ka2 = 6.2 *10¯8

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Which of the following indicators would be the best to use when 0.050 M benzoic acid (Ka = 6.6*10¯5) is titrated with 0.05 M NaOH?

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A solution is prepared by dissolving 20.0 g of K2HPO4 and 25.0 g of KH2PO4 in enough water to produce 1.0 L of solution. What is the pH of this buffer? For phosphoric acid (H3PO4), Ka2 = 6.2 *10¯8

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A change in pH will significantly affect the solubility of which, if any, of the following compounds?

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Buffer solutions with the component concentrations shown below were prepared. Which of them should have the lowest pH?

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Calculate the solubility of strontium fluoride, SrF2, in pure water. Ksp = 2.6 * 10¯9

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The solubility of calcium chromate is 1.56 *10¯3 g/100 mL of solution. What is the Ksp for CaCrO4?

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What is the pH of a buffer that consists of 0.45 M CH3COOH and 0.35 M CH3COONa? Ka = 1.8 *10¯5

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The salts X(NO3)2 and Y(NO3)2 (where X+ and Y+ are metal ions) are dissolved in water to give a solution which is 0.1 M in each of them. Using the Ksp values listed below, decide which aqueous reagent, if any, will definitely precipitate X+ before precipitating Y+ from solution. Given Ksp values: XCl2, 1 * 10¯5; YCl2, 1 * 10¯10; X(OH)2, 1 *10¯10; Y(OH)2, 1 * 10¯5

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The equivalence point in a titration is defined as the point when the indicator changes color.

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What is the [H3O+] in a solution that consists of 1.5 M NH3 and 2.5 NH4Cl? Kb = 1.8 * 10¯5

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A formic acid buffer containing 0.50 M HCOOH and 0.50 M HCOONa has a pH of 3.77. What will the pH be after 0.010 mol of NaOH has been added to 100.0 mL of the buffer?

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A buffer is to be prepared by adding solid sodium acetate to 0.10 M CH3COOH. Which of the following concentrations of sodium acetate will produce the most effective buffer?

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Write the ion product expression for magnesium fluoride, MgF2.

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When 0.300 g of a diprotic acid was titrated with 0.100 M LiOH, 40.0 mL of the LiOH solution was needed to reach the second equivalence point. Identify the formula of the diprotic acid.

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