Exam 10: Carboxylic Acids and Derivatives: Nucleophilic Acyl Substitution Reactions

What is the order of decreasing reactivity towards nucleophilic acyl substitution for the carboxylic acid derivatives? (most reactive first)

(Multiple Choice)

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Question 21

An ether solution contains the following components. If this solution is extracted with a 5% solution of NaHCO₃, that is immiscible with ether, which components end up in the ether layer and which in the NaHCO₃ layer?

(Essay)

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Question 22

Instructions: Provide the missing structure(s) or reagent(s) for each reaction or sequences of reactions. Show all relevant stereochemistry. -Provide missing structure(s):

(Essay)

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Question 23

Instructions: Consider the data in the table below to answer the following question(s). -Refer to instructions. Draw the structure of the strongest acid in the table.

(Essay)

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Question 24

Which of the following has the highest boiling point?

(Multiple Choice)

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Question 25

Instructions: Give the major organic product(s) for each of the following reactions or sequences of reactions. Show all relevant stereochemistry. -Give major product(s):

(Essay)

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Question 26

Instructions: Draw structures corresponding to each of the following IUPAC names. -Draw: 2,5-dihydroxybenzoic acid

(Essay)

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Question 27

Instructions: Consider the information below to answer the following question(s). The reaction of a carboxylic acid with an alcohol in the presence of acid is termed a Fischer esterification. -Refer to instructions. The nucleophile in this reaction is indicated by letter _____.

(Short Answer)

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Question 28

Which of the following is the correct order of decreasing reactivity in hydrolysis reactions (more reactive > less reactive)?

(Multiple Choice)

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Question 29

The product of the following reaction is a primary essence contained within bananas. a)Draw its structure. b)The product of the above reaction could also be produced by the reaction of an acid and an alcohol. Draw their structures.

(Essay)

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Question 30

What is the major organic product obtained from the following reaction?

(Multiple Choice)

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Question 31

Which of the following would represent the correct reaction conditions for the following conversion?

(Multiple Choice)

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Question 32

What is the major organic product obtained from the following reaction?

(Multiple Choice)

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Question 33

Complete the following reaction sequence with the missing major organic products.

(Essay)

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Question 34

Rank the following from highest to lowest reactivity toward reaction with EtOH.

(Short Answer)

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Question 35

Instructions: Give the major organic product(s) for each of the following reactions or sequences of reactions. Show all relevant stereochemistry. -Give the major product(s):

(Essay)

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Question 36

Instructions: Provide IUPAC names for the structures in the following question(s). -Name:

(Short Answer)

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Question 37

Instructions: Draw structures corresponding to each of the following IUPAC names. -Draw: 3-chlorobenzoic acid

(Essay)

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Question 38

What is the IUPAC name of the following compound?

(Multiple Choice)

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Question 39

Instructions: Provide the missing structure(s) or reagent(s) for each reaction or sequences of reactions. Show all relevant stereochemistry. -Provide missing structure(s):

(Essay)

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Question 40

Showing 21 - 40 of 63

What is the order of decreasing reactivity towards nucleophilic acyl substitution for the carboxylic acid derivatives? (most reactive first)

An ether solution contains the following components. If this solution is extracted with a 5% solution of NaHCO₃, that is immiscible with ether, which components end up in the ether layer and which in the NaHCO₃ layer?

Instructions: Provide the missing structure(s) or reagent(s) for each reaction or sequences of reactions. Show all relevant stereochemistry. -Provide missing structure(s):

Instructions: Consider the data in the table below to answer the following question(s). -Refer to instructions. Draw the structure of the strongest acid in the table.

Which of the following has the highest boiling point?

Instructions: Give the major organic product(s) for each of the following reactions or sequences of reactions. Show all relevant stereochemistry. -Give major product(s):

Instructions: Draw structures corresponding to each of the following IUPAC names. -Draw: 2,5-dihydroxybenzoic acid

Instructions: Consider the information below to answer the following question(s). The reaction of a carboxylic acid with an alcohol in the presence of acid is termed a Fischer esterification. -Refer to instructions. The nucleophile in this reaction is indicated by letter _____.

Which of the following is the correct order of decreasing reactivity in hydrolysis reactions (more reactive > less reactive)?

The product of the following reaction is a primary essence contained within bananas. a)Draw its structure. b)The product of the above reaction could also be produced by the reaction of an acid and an alcohol. Draw their structures.

What is the major organic product obtained from the following reaction?

Which of the following would represent the correct reaction conditions for the following conversion?

What is the major organic product obtained from the following reaction?

Complete the following reaction sequence with the missing major organic products.

Rank the following from highest to lowest reactivity toward reaction with EtOH.

Instructions: Give the major organic product(s) for each of the following reactions or sequences of reactions. Show all relevant stereochemistry. -Give the major product(s):

Instructions: Provide IUPAC names for the structures in the following question(s). -Name:

Instructions: Draw structures corresponding to each of the following IUPAC names. -Draw: 3-chlorobenzoic acid

What is the IUPAC name of the following compound?

Instructions: Provide the missing structure(s) or reagent(s) for each reaction or sequences of reactions. Show all relevant stereochemistry. -Provide missing structure(s):

Structure and Bonding:acids and Bases

Alkanes: the Nature of Organic Compounds

Alkenes and Alkynes: the Nature of Organic Reactions

Reactions of Alkenes and Alkynes

Aromatic Compounds

Sterechemistry at Tetrahedral Centers

Organohalides: Nucleophilic Substitutions and Eliminations

Alcohols, Phenols, Ethers, and Their Sulfur Analogs

Aldehydes and Ketones: Nucleophilic Addition Reactions

Carbonyl Alpha-Substitution Reactions and Condensation Reactions

Amines

Structure Determination

Biomolecules: Carbohydrates

Biomolecules: Amino Acids, Peptides, and Proteins

Biomolecules: Lipids and Nucleic Acids

The Organic Chemistry of Metabolic Pathways

Filters

Exam 10: Carboxylic Acids and Derivatives: Nucleophilic Acyl Substitution Reactions

What is the order of decreasing reactivity towards nucleophilic acyl substitution for the carboxylic acid derivatives? (most reactive first)

An ether solution contains the following components. If this solution is extracted with a 5% solution of NaHCO3, that is immiscible with ether, which components end up in the ether layer and which in the NaHCO3 layer?

Instructions: Provide the missing structure(s) or reagent(s) for each reaction or sequences of reactions. Show all relevant stereochemistry. -Provide missing structure(s):

Instructions: Consider the data in the table below to answer the following question(s). -Refer to instructions. Draw the structure of the strongest acid in the table.

Which of the following has the highest boiling point?

Instructions: Give the major organic product(s) for each of the following reactions or sequences of reactions. Show all relevant stereochemistry. -Give major product(s):

Instructions: Draw structures corresponding to each of the following IUPAC names. -Draw: 2,5-dihydroxybenzoic acid

Instructions: Consider the information below to answer the following question(s). The reaction of a carboxylic acid with an alcohol in the presence of acid is termed a Fischer esterification. -Refer to instructions. The nucleophile in this reaction is indicated by letter _____.

Which of the following is the correct order of decreasing reactivity in hydrolysis reactions (more reactive > less reactive)?

The product of the following reaction is a primary essence contained within bananas. a)Draw its structure. b)The product of the above reaction could also be produced by the reaction of an acid and an alcohol. Draw their structures.

What is the major organic product obtained from the following reaction?

Which of the following would represent the correct reaction conditions for the following conversion?

What is the major organic product obtained from the following reaction?

Complete the following reaction sequence with the missing major organic products.

Rank the following from highest to lowest reactivity toward reaction with EtOH.

Instructions: Give the major organic product(s) for each of the following reactions or sequences of reactions. Show all relevant stereochemistry. -Give the major product(s):

Instructions: Provide IUPAC names for the structures in the following question(s). -Name:

Instructions: Draw structures corresponding to each of the following IUPAC names. -Draw: 3-chlorobenzoic acid

What is the IUPAC name of the following compound?

Instructions: Provide the missing structure(s) or reagent(s) for each reaction or sequences of reactions. Show all relevant stereochemistry. -Provide missing structure(s):

Structure and Bonding:acids and Bases

Alkanes: the Nature of Organic Compounds

Alkenes and Alkynes: the Nature of Organic Reactions

Reactions of Alkenes and Alkynes

Aromatic Compounds

Sterechemistry at Tetrahedral Centers

Organohalides: Nucleophilic Substitutions and Eliminations

Alcohols, Phenols, Ethers, and Their Sulfur Analogs

Aldehydes and Ketones: Nucleophilic Addition Reactions

Carbonyl Alpha-Substitution Reactions and Condensation Reactions

Amines

Structure Determination

Biomolecules: Carbohydrates

Biomolecules: Amino Acids, Peptides, and Proteins

Biomolecules: Lipids and Nucleic Acids

The Organic Chemistry of Metabolic Pathways

Filters

An ether solution contains the following components. If this solution is extracted with a 5% solution of NaHCO₃, that is immiscible with ether, which components end up in the ether layer and which in the NaHCO₃ layer?