Exam 23: Transition Metals and Coordination Chemistry

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Based on the crystal-field strengths Cl- < F- < H2O < NH3 < H2NC2H4NH2, which octahedral Ti(III)complex below has its d-d electronic transition at shortest wavelength?

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In humans, what percent of absorbed iron is found in blood?

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Which one of the following ions cannot form both a high spin and a low spin octahedral complex ion?

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What is a siderophore?

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In the compound, CaNa[Fe(CN)6], what ligands are in the coordination sphere?

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Most transition metal ions contain partially occupied __________ subshells.

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A complex of correctly written formula [Pt(NH3)3Br]BrH2O has which set of ligands in its inner coordination sphere?

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The chelate effect must always occur with positive enthalpy change.

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How many iron atoms are coordinated in a hemoglobin molecule?

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Linkage isomerism can only occur __________.

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Complexes containing metals with d10 electron configurations are typically colorless because

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What is the coordination number of chromium in [Cr(H2O)4Cl2]+?

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The coordination number and oxidation number of the central atom in [Mn(CO)4Br2] are __________ and __________, respectively.

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What colors of light does chlorophyll-a absorb?

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The minimum number of unshared valence electron pairs in the ligands of a coordination compound is __________.

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What is the oxidation state of iron in CaNa[Fe(CN)6]?

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The color of hemoglobin changes from purple to red when water displaces oxygen on the molecule.

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EDTA is __________-dantate ligand.

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The correct name for [Cu(NH3)4(H2O)2]+2 is __________.

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Name the compound, Ca[AlH4]2.

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