Exam 21: Transition Metal Complexes

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A student wants to make 3-nitro-1-phenyl-1-butyne using Sonogahira coupling conditions,beginning with iodobenzene.This student will also require ____ in order to make this product.

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Consider the following reaction.The complex in the middle underwent a(n)_____ reaction to make the final product. Consider the following reaction.The complex in the middle underwent a(n)_____ reaction to make the final product.

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Coupling an aryl tin reagent with an alkenyl halide,using a Pd catalyst,is an example of ____.

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Consider the transition metal complex Ni(CN)3(H2O)23-.The total number of valence electrons this complex possesses is ____.

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A student wants to make 4-nitro-1-phenyl-1-butyne using Sonogahira coupling conditions,beginning with iodobenzene.This student will also require ____ in order to make this product.

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Sonogashira and ____ reagents both make use of copper reagents in order to perform cross-coupling reactions.

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The total number of valence electrons contributed by all nitrogen atoms toward Re is ____. The total number of valence electrons contributed by all nitrogen atoms toward Re is ____.

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An 18 electron complex loses a ligand to become a 16 electron complex.This is an example of a(n)____ reaction.

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The fifth step in the mechanism of an alkene reacting with Wilkinson's catalyst is ____.

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The third step in the mechanism of an alkene reacting with Wilkinson's catalyst is ____.

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Consider the transition metal complex Pd(PPh3)4.The total number of valence electrons this complex possesses is ____.

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Coupling a terminal alkyne with an alkenyl halide,using a mixture of a Pd and Cu(I)catalyst,is an example of ____.

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Reacting 2-nitrostyrene with iodobenzene under Heck-Mizoroki conditions will generate ____ as its product.

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Converting an alkene to an alkane using the catalyst Pd/C is ____ hydrogenation.

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In the third step in olefin metathesis the ____.

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Which choice could provide the product. _______ + _______ Which choice could provide the product. _______ + _______    Which choice could provide the product. _______ + _______

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The first step in olefin metathesis has the metal alkylidene ([M]=)reacting with an alkene by ____ addition to form a ____ .

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The valence electron count for Cr in CrC6H6(CO)3 is ____.

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Transition metals can react with a variety of molecules called ____.

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Reacting 1-pentyne with iodobenzene in the presence of CuI,Pd catalyst (in an amine base)will generate ____ as its product.

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