Exam 17: Properties of Solutions

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Calculate the molality of C2H5OH in a water solution that is prepared by mixing 50.0 mL of C2H5OH with 100.0 mL of H2O at 20°C. The density of the C2H5OH is 0.789 g/mL at 20°C.

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At a given temperature, the vapor pressure of heptane is 92.0 torr and the vapor pressure of octane is 31.2 torr. Assuming ideal behavior, what is the vapor pressure of a solution that contains three times as many moles of octane as heptane?

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50.0g of pure sand (silica) is poured into 1 L of water where it immediately sinks to the bottom and remains undissolved. Which of the following is true?

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Polyethylene is a synthetic polymer or plastic with many uses. 1.40 g of a polyethylene sample was dissolved in enough benzene to make 100. mL of solution, and the osmotic pressure was found to be 1.86 torr at 25°C. What is the molar mass of the polyethylene?

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The molar mass of a solid as determined by freezing-point depression is 10% higher than the true molar mass. Which of the following experimental errors could not account for this discrepancy?

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An aqueous solution contains 171.2 g of NaCl per liter. What is the molarity of the solution?

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The boiling point of pure benzene at 760. torr is 80.1°C. What is the vapor pressure of benzene over a solution containing 4.40 mol of nonvolatile hydrocarbon and 11.80 mol of benzene at 80.1°C?

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Using the data below, calculate the vapor pressure of chloroform over a chloroform-benzene solution at 25°C, which contains 50.0 g of CHCl3 and 50.0 g of C6H6. Assume that the solution behaves ideally. Using the data below, calculate the vapor pressure of chloroform over a chloroform-benzene solution at 25°C, which contains 50.0 g of CHCl<sub>3</sub> and 50.0 g of C<sub>6</sub>H<sub>6</sub>. Assume that the solution behaves ideally.

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When 200.0 mL of 0.200 M H2SO4 is diluted with 155.0 mL of water, what is the molarity of the solution?

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For each of the following solutions, would you expect it with respect to Raoult's law) to be relatively ideal, to show a positive deviation, or to show a negative deviation? -hexane (C6H14) and chloroform (CHCl3)

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What is the percentage by mass of glycerol (C3H5(OH)3) in a 1.5 m solution?

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Adding salt to water decreases the freezing point of the water because it lowers the vapor pressure of the ice.

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Determine the molarity of a solution containing 2.00 g of sodium hydroxide in 250.0 mL of solution.

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When 1 mol of a nonvolatile solvent-nondissociating substance is dissolved in 3 mol of solvent, the ratio of vapor pressure of the solution to that of the pure solvent (at the same temperature) is approximately

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Calculate the mole fraction of C12H22O11 in a solution prepared by dissolving 250.0 g of C12H22O11 in 1.00 kg of H2O.

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Solid KF has a lattice energy of -804 kJ/mol and a heat of solution (in water) of -15 kJ/mol. RbF has a lattice energy of -768 kJ/mol and a heat of solution (in water) of -24 kJ/mol. Which salt forms stronger attractions with water?

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A chemist is given a white solid that is suspected of being pure cocaine. When 1.22 g of the solid is dissolved in 15.60 g of benzene, the freezing point is lowered by 1.32°C. Calculate the molar mass of the solid. The molal freezing-point constant (Kf) for benzene is 5.12°C/m.

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At a given temperature, you have a mixture of benzene (vapor pressure of pure benzene = 745 torr) and toluene (vapor pressure of pure toluene = 290 torr). The mole fraction of benzene in the vapor above the solution is 0.590. Assuming ideal behavior, calculate the mole fraction of toluene in the solution.

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For each of the following solutions, would you expect it with respect to Raoult's law) to be relatively ideal, to show a positive deviation, or to show a negative deviation? -hexane (C6H14) and octane (C8H18)

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When a 1.50-g sample of glutamic acid is dissolved in 100.0 g of H2O, the resulting solution freezes at -0.190°C. Kf for H2O is 1.86°C/m. The molar mass of glutamic acid is

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