Question 1

Predict the product for the following reaction.

Accepted Answer

A)  I 
B)  II 
C)  III 
D)  IV 
E)  None of these 
A)  I 
B)  II 
C)  III 
D)  IV 
E)  None of these C

Question 2

Predict the product for the following reaction.

Accepted Answer

A)  I 
B)  II 
C)  III 
D)  IV 
E)  I & II 
A)  I 
B)  II 
C)  III 
D)  IV 
E)  I & II B

Question 3

Predict the product for the following reaction.

Accepted Answer

A)  I 
B)  II 
C)  III 
D)  IV 
E)  V 
A)  I 
B)  II 
C)  III 
D)  IV 
E)  V C

Question 4

Which of the following is a secondary alkyl halide?

Accepted Answer

A)  1-Bromo-2-methylpropane 
B)  2-Bromopropane 
C)  1-Bromobutane 
D)  2-Bromo-2-methylpropane 
A)  1-Bromo-2-methylpropane 
B)  2-Bromopropane 
C)  1-Bromobutane 
D)  2-Bromo-2-methylpropane

Question 5

Provide a curved arrow mechanism and predict the product for the following reaction.

Accepted Answer

The answer of Provide a curved arrow mechanism and predict...

Question 6

Which of the following is a strongest nucleophile in a polar protic solvent?

Accepted Answer

A)  F- 
B)  Cl- 
C)  OH- 
D)  SH- 
E)  All of these 
A)  F- 
B)  Cl- 
C)  OH- 
D)  SH- 
E)  All of these

Question 7

Rank the following compounds from most to least reactive in an SN1 reaction.

Accepted Answer

A)  I>IV>II>III 
B)  II>I>IV>III 
C)  III>IV>I>II 
D)  IV>I>II>III 
E)  IV>III>I>II 
A)  I>IV>II>III 
B)  II>I>IV>III 
C)  III>IV>I>II 
D)  IV>I>II>III 
E)  IV>III>I>II

Question 8

Provide a curved arrow mechanism for the following reaction.

Accepted Answer

The answer of Provide a curved arrow mechanism for the...

Question 9

Predict the major product for the following reaction.

Accepted Answer

A)  I 
B)  II 
C)  Both I & III 
D)  Both II & IV 
E)  None of these 
A)  I 
B)  II 
C)  Both I & III 
D)  Both II & IV 
E)  None of these

Question 10

Predict the product for the following reaction.

Accepted Answer

The answer of Predict the product for the following reaction....

Question 11

When drawing a curved arrow mechanism, the tail of the arrow starts at______.

Accepted Answer

A)  the bond that is being formed 
B)  the atom with the positive charge 
C)  the source of electrons that is being moved 
D)  the location to which the electrons are being moved 
A)  the bond that is being formed 
B)  the atom with the positive charge 
C)  the source of electrons that is being moved 
D)  the location to which the electrons are being moved

Question 12

Predict the product(s) for the following reaction.

Accepted Answer

A)  Both I & IV 
B)  II 
C)  III 
D)  IV 
E)  Both II & III 
A)  Both I & IV 
B)  II 
C)  III 
D)  IV 
E)  Both II & III

Question 13

Provide the reagents necessary to carry out the following conversion.

Accepted Answer

A)  H2S in water 
B)  H2S in DMSO 
C)  NaSH in water 
D)  NaSH in DMSO 
A)  H2S in water 
B)  H2S in DMSO 
C)  NaSH in water 
D)  NaSH in DMSO

Question 14

Provide a curved arrow mechanism for the following reaction.

Accepted Answer

The answer of Provide a curved arrow mechanism for the...

Question 15

Predict the product for the following reaction.

Accepted Answer

A)  I 
B)  II 
C)  III 
D)  IV 
E)  V 
A)  I 
B)  II 
C)  III 
D)  IV 
E)  V

Question 16

Provide a curved arrow mechanism and predict the product for the following reaction.

Accepted Answer

The answer of Provide a curved arrow mechanism and predict...

Question 17

Which of the following alkyl halides will undergo the fastest SN2 reaction?

Accepted Answer

A)  I 
B)  II 
C)  III 
D)  IV 
E)  V 
A)  I 
B)  II 
C)  III 
D)  IV 
E)  V

Question 18

Provide the structure for cis-1,2-dibromocyclopentane.

Accepted Answer

The answer of Provide the structure for cis-1,2-dibromocyclopentane....

Question 19

Which of the following is an aprotic solvent?

Accepted Answer

A)  I- 
B)  II- 
C)  III 
D)  IV 
E)  none of these 
A)  I- 
B)  II- 
C)  III 
D)  IV 
E)  none of these

Question 20

Which of the following is a weak nucleophile?

Accepted Answer

A)  OH- 
B)  H2O 
C)  CH3O- 
D)  NH3 
E)  All of these 
A)  OH- 
B)  H2O 
C)  CH3O- 
D)  NH3 
E)  All of these

Exam 7: Substitution Reactions

Predict the product for the following reaction.

Predict the product for the following reaction.

Predict the product for the following reaction.

Which of the following is a secondary alkyl halide?

Provide a curved arrow mechanism and predict the product for the following reaction.

Which of the following is a strongest nucleophile in a polar protic solvent?

Rank the following compounds from most to least reactive in an SN1 reaction.

Provide a curved arrow mechanism for the following reaction.

Predict the major product for the following reaction.

Predict the product for the following reaction.

When drawing a curved arrow mechanism, the tail of the arrow starts at______.

Predict the product(s) for the following reaction.

Provide the reagents necessary to carry out the following conversion.

Provide a curved arrow mechanism for the following reaction.

Predict the product for the following reaction.

Provide a curved arrow mechanism and predict the product for the following reaction.

Which of the following alkyl halides will undergo the fastest SN2 reaction?

Provide the structure for cis-1,2-dibromocyclopentane.

Which of the following is an aprotic solvent?

Which of the following is a weak nucleophile?

A Review of General Chemistry: Electrons, Bonds, and Molecular Properties

Molecular Representations

Acids and Bases

Alkanes and Cycloalkanes

Stereoisomerism

Chemical Reactivity and Mechanisms

Alkenes: Structure and Preparation Via Elimination Reactions

Addition Reactions of Alkenes

Alkynes

Radical Reactions

Synthesis

Alcohols and Phenols

Ethers and Epoxides; Thiols and Sulfides

Infrared Spectroscopy and Mass Spectrometry

Nuclear Magnetic Resonance Spectroscopy

Conjugated Pi Systems and Pericyclic Reactions

Aromatic Compounds

Aromatic Substitution Reactions

Aldehydes and Ketones

Carboxylic Acids and Their Derivatives

Alpha Carbon Chemistry: Enols and Enolates

Amines

Carbohydrates

Amino Acids, Peptides, and Proteins

Lipids

Synthetic Polymers

Filters

Rank the following compounds from most to least reactive in an S_N1 reaction.

Which of the following alkyl halides will undergo the fastest S_N2 reaction?