Question 1

Draw the potential energy diagram for the following reaction.

Accepted Answer

A)  I 
B)  II 
C)  III 
D)  IV 
A)  I 
B)  II 
C)  III 
D)  IV

Question 2

Which of the following potential energy diagram represent an exothermic concerted reaction?

Accepted Answer

A)  I 
B)  II 
C)  III 
D)  IV 
A)  I 
B)  II 
C)  III 
D)  IV

Question 3

What is the IUPAC name for the following compound?

Accepted Answer

2-bromo-5-

Question 4

Provide a curved arrow mechanism for the following reaction.

Accepted Answer

The answer of Provide a curved arrow mechanism for the...

Question 5

Which of the following is a weakest nucleophile in a polar protic solvent?

Accepted Answer

A)  F- 
B)  Cl- 
C)  Br- 
D)  I- 
E)  All of these 
A)  F- 
B)  Cl- 
C)  Br- 
D)  I- 
E)  All of these

Question 6

Which of the following is a tertiary alkyl halide?

Accepted Answer

A)  1-Bromo-2-methylpropane 
B)  2-Bromopropane 
C)  1-Bromobutane 
D)  2-Bromo-2-methylpropane 
A)  1-Bromo-2-methylpropane 
B)  2-Bromopropane 
C)  1-Bromobutane 
D)  2-Bromo-2-methylpropane

Question 7

Predict the product and provide a curved arrow mechanism for the formation of the product.

Accepted Answer

The answer of Predict the product and provide a curved...

Question 8

What substitution reaction mechanism is most likely for the following compound?

Accepted Answer

A)  SN1 
B)  SN2 
C)  Either SN1 or SN2 
D)  None of these 
A)  SN1 
B)  SN2 
C)  Either SN1 or SN2 
D)  None of these

Question 9

Predict the major product for the following reaction and provide a curved arrow mechanism for the formation of the product.

Accepted Answer

The answer of Predict the major product for the following...

Question 10

Predict the product(s) for the following reaction.

Accepted Answer

The answer of Predict the product(s) for the following reaction....

Question 11

What is the correct structure for (2S,5R)-2-fluoro-5-methylnonane?

Accepted Answer

A)  I 
B)  II 
C)  III 
D)  IV 
A)  I 
B)  II 
C)  III 
D)  IV

Question 12

Provide the structure for 1-chloro-4-isopropylheptane.

Accepted Answer

The answer of Provide the structure for 1-chloro-4-isopropylheptane....

Question 13

What is the IUPAC name for the following compound?

Accepted Answer

A)  3-Fluorobutane 
B)  2-Fluorobutane 
C)  (S)-2-Fluorobutane 
D)  (R)-2-Fluorobutane 
A)  3-Fluorobutane 
B)  2-Fluorobutane 
C)  (S)-2-Fluorobutane 
D)  (R)-2-Fluorobutane

Question 14

Provide a curved arrow mechanism for the following reaction.

Accepted Answer

The answer of Provide a curved arrow mechanism for the...

Question 15

Predict the major product(s) and provide a curved arrow mechanism for the formation of the product.

Accepted Answer

The answer of Predict the major product(s) and provide a...

Question 16

Provide the reagents necessary to carry out the following conversion.

Accepted Answer

A)  HN3 in water 
B)  HN3 in acetonitrile 
C)  NaN3 in water 
D)  NaN3 in acetonitrile 
A)  HN3 in water 
B)  HN3 in acetonitrile 
C)  NaN3 in water 
D)  NaN3 in acetonitrile

Question 17

Which of the following compounds will undergo rearrangement during solvolysis reaction?

Accepted Answer

A)  3-iodo-2-methylheptane 
B)  3-iodo-5-methylheptane 
C)  3-iodo-3-methylheptane 
D)  3-iodoheptane 
E)  cis-1-iodo-3-methylcyclohexane 
A)  3-iodo-2-methylheptane 
B)  3-iodo-5-methylheptane 
C)  3-iodo-3-methylheptane 
D)  3-iodoheptane 
E)  cis-1-iodo-3-methylcyclohexane

Question 18

Provide the reagents necessary to carry out the following conversion.

Accepted Answer

The answer of Provide the reagents necessary to carry out...

Question 19

Provide a curved arrow mechanism for the following reaction.

Accepted Answer

The answer of Provide a curved arrow mechanism for the...

Question 20

Provide the reagents necessary to carry out the following conversion.

Accepted Answer

The answer of Provide the reagents necessary to carry out...

Exam 7: Substitution Reactions

Draw the potential energy diagram for the following reaction.

Which of the following potential energy diagram represent an exothermic concerted reaction?

What is the IUPAC name for the following compound?

Provide a curved arrow mechanism for the following reaction.

Which of the following is a weakest nucleophile in a polar protic solvent?

Which of the following is a tertiary alkyl halide?

Predict the product and provide a curved arrow mechanism for the formation of the product.

What substitution reaction mechanism is most likely for the following compound?

Predict the major product for the following reaction and provide a curved arrow mechanism for the formation of the product.

Predict the product(s) for the following reaction.

What is the correct structure for (2S,5R)-2-fluoro-5-methylnonane?

Provide the structure for 1-chloro-4-isopropylheptane.

What is the IUPAC name for the following compound?

Provide a curved arrow mechanism for the following reaction.

Predict the major product(s) and provide a curved arrow mechanism for the formation of the product.

Provide the reagents necessary to carry out the following conversion.

Which of the following compounds will undergo rearrangement during solvolysis reaction?

Provide the reagents necessary to carry out the following conversion.

Provide a curved arrow mechanism for the following reaction.

Provide the reagents necessary to carry out the following conversion.

A Review of General Chemistry: Electrons, Bonds, and Molecular Properties

Molecular Representations

Acids and Bases

Alkanes and Cycloalkanes

Stereoisomerism

Chemical Reactivity and Mechanisms

Alkenes: Structure and Preparation Via Elimination Reactions

Addition Reactions of Alkenes

Alkynes

Radical Reactions

Synthesis

Alcohols and Phenols

Ethers and Epoxides; Thiols and Sulfides

Infrared Spectroscopy and Mass Spectrometry

Nuclear Magnetic Resonance Spectroscopy

Conjugated Pi Systems and Pericyclic Reactions

Aromatic Compounds

Aromatic Substitution Reactions

Aldehydes and Ketones

Carboxylic Acids and Their Derivatives

Alpha Carbon Chemistry: Enols and Enolates

Amines

Carbohydrates

Amino Acids, Peptides, and Proteins

Lipids

Synthetic Polymers

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