Exam 1: Introduction and Review

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Draw a correct Lewis structure for boric acid, B(OH)3.

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  or  or   or

For most compounds in which a nitrogen atom bears no formal charge, the valence of this nitrogen atom is ________.

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3

Write a completed equation for the acid-base pair shown below. HCN + NaOH →

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HCN + NaOH → NaCN + H2O

Provide the line-angle formula (skeletal structure) for CH2=CHCH2CH2C(CH3)3.

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Draw the line energy orbital diagram for the outer shell of an uncharge nitrogen atom and describe the location and number of unshared electrons.

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Write a completed equation for the acid-base pair shown below. HCO2H + -NH2

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Draw a correct Lewis structure for (CH3)2CHCOOH.

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Nitroamines are common functional groups found in energetic materials, such as RDX and HMX. For the structure below, draw two other significant resonance structures, include any formal charges, and indicate the hybridization on each nitrogen and oxygen. Nitroamines are common functional groups found in energetic materials, such as RDX and HMX. For the structure below, draw two other significant resonance structures, include any formal charges, and indicate the hybridization on each nitrogen and oxygen.

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Provide the products of the following acid-base reaction. (CH3)3NH+ + HO-

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Which sequence correctly ranks the following protons in order of increasing pKa value? Which sequence correctly ranks the following protons in order of increasing pK<sub>a</sub> value?

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Draw the important resonance forms for the structure shown below. Draw the important resonance forms for the structure shown below.

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The compound phenol is shown below. Provide the structure of the conjugate base of phenol. The compound phenol is shown below. Provide the structure of the conjugate base of phenol.

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Draw a correct Lewis structure for acetaldehyde, CH3CHO.

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Provide the line-angle formula (skeletal structure) for (CH3CH2)2C=O.

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Which of the following molecules contains a polar covalent bond?

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What is the molecular formula for the molecule shown? What is the molecular formula for the molecule shown?

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Draw a correct Lewis structure for acetonitrile, CH3CN.

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Provide the line-angle formula for CH3CH2C(CH3)2CH2CHO

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The pH of a 150 mL aqueous solution of 2.13 x 10-3 M HCl is ________.

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Which is more acidic, HF or HI? Explain.

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