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Thiols (R-S-H) Undergo Addition to Alkenes but Only in the Presence

Question 1

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Thiols (R-S-H) undergo addition to alkenes but only in the presence of peroxides. This equation is an example.
(CH3) 2C=CH2+RSH peroxides (CH3) 2CHCH2SR\left( \mathrm { CH } _ { 3 } \right) _ { 2 } \mathrm { C } = \mathrm { CH } _ { 2 } + \mathrm { RSH } \stackrel { \text { peroxides } } { \longrightarrow } \left( \mathrm { CH } _ { 3 } \right) _ { 2 } \mathrm { CH } - \mathrm { CH } _ { 2 } \mathrm { SR } Which one of these is a reactive intermediate in this reaction?
(a) (CH3) 2CC˙H2SR\left( \mathrm { CH } _ { 3 } \right) _ { 2 } \mathrm { C } - \dot { \mathrm { C } } \mathrm { H } _ { 2 } - \mathrm { SR }
(b)
 Thiols (R-S-H)  undergo addition to alkenes but only in the presence of peroxides. This equation is an example.  \left( \mathrm { CH } _ { 3 } \right)  _ { 2 } \mathrm { C } = \mathrm { CH } _ { 2 } + \mathrm { RSH } \stackrel { \text { peroxides } } { \longrightarrow } \left( \mathrm { CH } _ { 3 } \right)  _ { 2 } \mathrm { CH } - \mathrm { CH } _ { 2 } \mathrm { SR }  Which one of these is a reactive intermediate in this reaction? (a)   \left( \mathrm { CH } _ { 3 } \right)  _ { 2 } \mathrm { C } - \dot { \mathrm { C } } \mathrm { H } _ { 2 } - \mathrm { SR }  (b)    (c)   \left( \mathrm { CH } _ { 3 } \right)  _ { 2 } \stackrel { + } { \mathrm { C } } - \mathrm { CH } _ { 2 } - \mathrm { SR }   (d)   \left( \mathrm { CH } _ { 3 } \right)  _ { 2 } \dot { \mathrm { C } } - \mathrm { CH } _ { 2 } - \mathrm { SR }   (e)     (f)   \left( \mathrm { CH } _ { 3 } \right)  _ { 2 } \dot { \mathrm { C } } - \mathrm { CH } _ { 2 } - \mathrm { SH }  A)  compound (a)  B)  compound (b)  C)  compound (c)  D)  compound (d)  E)  compound (e) f.  compound (f)
(c) (CH3) 2C+CH2SR\left( \mathrm { CH } _ { 3 } \right) _ { 2 } \stackrel { + } { \mathrm { C } } - \mathrm { CH } _ { 2 } - \mathrm { SR }

(d) (CH3) 2C˙CH2SR\left( \mathrm { CH } _ { 3 } \right) _ { 2 } \dot { \mathrm { C } } - \mathrm { CH } _ { 2 } - \mathrm { SR }

(e)
 Thiols (R-S-H)  undergo addition to alkenes but only in the presence of peroxides. This equation is an example.  \left( \mathrm { CH } _ { 3 } \right)  _ { 2 } \mathrm { C } = \mathrm { CH } _ { 2 } + \mathrm { RSH } \stackrel { \text { peroxides } } { \longrightarrow } \left( \mathrm { CH } _ { 3 } \right)  _ { 2 } \mathrm { CH } - \mathrm { CH } _ { 2 } \mathrm { SR }  Which one of these is a reactive intermediate in this reaction? (a)   \left( \mathrm { CH } _ { 3 } \right)  _ { 2 } \mathrm { C } - \dot { \mathrm { C } } \mathrm { H } _ { 2 } - \mathrm { SR }  (b)    (c)   \left( \mathrm { CH } _ { 3 } \right)  _ { 2 } \stackrel { + } { \mathrm { C } } - \mathrm { CH } _ { 2 } - \mathrm { SR }   (d)   \left( \mathrm { CH } _ { 3 } \right)  _ { 2 } \dot { \mathrm { C } } - \mathrm { CH } _ { 2 } - \mathrm { SR }   (e)     (f)   \left( \mathrm { CH } _ { 3 } \right)  _ { 2 } \dot { \mathrm { C } } - \mathrm { CH } _ { 2 } - \mathrm { SH }  A)  compound (a)  B)  compound (b)  C)  compound (c)  D)  compound (d)  E)  compound (e) f.  compound (f)

(f) (CH3) 2C˙CH2SH\left( \mathrm { CH } _ { 3 } \right) _ { 2 } \dot { \mathrm { C } } - \mathrm { CH } _ { 2 } - \mathrm { SH }


A) compound (a)
B) compound (b)
C) compound (c)
D) compound (d)
E) compound (e) f.
compound (f)

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