Question 1

Which of the following is the correct IUPAC name of the following structure?

Accepted Answer

A) Chlorocyclopentane 
B) 2-Chloro-1-methylcyclopentane 
C) 1-Methyl-2-chlorocyclopentane 
D) 1-Chloro-2-methylcyclopentane 
A) Chlorocyclopentane 
B) 2-Chloro-1-methylcyclopentane 
C) 1-Methyl-2-chlorocyclopentane 
D) 1-Chloro-2-methylcyclopentane

Question 2

Given the following rate law,what will happen to the rate if the concentration of MeI is doubled? Rate = k[Me3N][MeI]

Accepted Answer

A) It will be doubled. 
B) It will not change. 
C) It will decrease in half. 
D) It will increase very slightly. 
A) It will be doubled. 
B) It will not change. 
C) It will decrease in half. 
D) It will increase very slightly.

Question 3

What reaction mechanism is most likely for substitution on the following compound?

Accepted Answer

A) SN1 
B) SN2 
C) Either 
D) Neither 
A) SN1 
B) SN2 
C) Either 
D) Neither

Question 4

Identify the labeled carbon as primary,secondary,or tertiary.

Accepted Answer

The answer of Identify the labeled carbon as primary,secondary,or tertiary....

Question 5

Write the rate law for the following SN2 reaction.

Accepted Answer

Question 6

What is the best leaving group in the following compound?

Accepted Answer

The answer of What is the best leaving group in...

Question 7

For the following reaction,which of the following is the rate law?

Accepted Answer

A) Rate = k[MeI] 
B) Rate = k[t-butanol] 
C) Rate = k[MeI][t-butanol] 
D) Rate = k[OH] 
A) Rate = k[MeI] 
B) Rate = k[t-butanol] 
C) Rate = k[MeI][t-butanol] 
D) Rate = k[OH]

Question 8

Provide a mechanism for this reaction.

Accepted Answer

The answer of Provide a mechanism for this reaction. ...

Question 9

Provide an IUPAC name for the following compound.

Accepted Answer

1,1-Dibrom

Question 10

When drawing an arrow-pushing mechanism,the tail of the arrow starts where?

Accepted Answer

A) At the bond that is being formed. 
B) At the bond that is being broken. 
C) At the source of electrons that is being moved. 
D) At the location to which the electrons are being moved. 
A) At the bond that is being formed. 
B) At the bond that is being broken. 
C) At the source of electrons that is being moved. 
D) At the location to which the electrons are being moved.

Question 11

For the following reaction,provide an energy diagram.

Accepted Answer

The answer of For the following reaction,provide an energy diagram....

Question 12

Draw an energy diagram for the following reaction.

Accepted Answer

The answer of Draw an energy diagram for the following...

Question 13

For the following reaction,which of the following is the mechanism?

Accepted Answer

A) SN1 
B) SN2 
C) Protonation 
D) Elimination 
A) SN1 
B) SN2 
C) Protonation 
D) Elimination

Question 14

Why do polar aprotic solvents favor SN2 reactions?

Accepted Answer

They raise the energy of the n

Question 15

What reaction mechanism is most likely for substitution on the following compound?

Accepted Answer

A) SN1 
B) SN2 
C) Either 
D) Neither 
A) SN1 
B) SN2 
C) Either 
D) Neither

Question 16

Provide an arrow pushing mechanism and product for the following reaction.

Accepted Answer

The answer of Provide an arrow pushing mechanism and product...

Question 17

Draw a mechanism for the following reaction.

Accepted Answer

The answer of Draw a mechanism for the following reaction....

Question 18

Which of the following is the correct IUPAC name of the following structure?

Accepted Answer

A) 2-Bromo-3-butylpentane 
B) (2S)-Bromo-4,5-dimethylheptane 
C) 3,4-Dimethyl-6-bromoheptane 
D) 2-Bromo-4-methylhexane 
A) 2-Bromo-3-butylpentane 
B) (2S)-Bromo-4,5-dimethylheptane 
C) 3,4-Dimethyl-6-bromoheptane 
D) 2-Bromo-4-methylhexane

Question 19

What is the anticipated major product for the following reaction?

Accepted Answer

The answer of What is the anticipated major product for...

Question 20

Provide the product of the following reaction.

Accepted Answer

The answer of Provide the product of the following reaction....

Exam 7: Substitution Reactions

Which of the following is the correct IUPAC name of the following structure?

Given the following rate law,what will happen to the rate if the concentration of MeI is doubled? Rate = k[Me3N][MeI]

What reaction mechanism is most likely for substitution on the following compound?

Identify the labeled carbon as primary,secondary,or tertiary.

Write the rate law for the following SN2 reaction.

What is the best leaving group in the following compound?

For the following reaction,which of the following is the rate law?

Provide a mechanism for this reaction.

Provide an IUPAC name for the following compound.

When drawing an arrow-pushing mechanism,the tail of the arrow starts where?

For the following reaction,provide an energy diagram.

Draw an energy diagram for the following reaction.

For the following reaction,which of the following is the mechanism?

Why do polar aprotic solvents favor SN2 reactions?

What reaction mechanism is most likely for substitution on the following compound?

Provide an arrow pushing mechanism and product for the following reaction.

Draw a mechanism for the following reaction.

Which of the following is the correct IUPAC name of the following structure?

What is the anticipated major product for the following reaction?

Provide the product of the following reaction.

A Review of General Chemistry: Electrons, Bonds, and Molecular Properties

Molecular Representations

Acids and Bases

Alkanes and Cycloalkanes

Stereoisomerism

Chemical Reactivity and Mechanisms

Alkenes: Structure and Preparation Via Elimination Reactions

Addition Reactions of Alkenes

Alkynes

Radical Reactions

Synthesis

Alcohols and Phenols

Ethers and Epoxides; Thiols and Sulfides

Nuclear Magnetic Resonance Spectroscopy

Infrared Spectroscopy and Mass Spectrometry

Conjugated Pi Systems and Pericyclic Reactions

Aromatic Compounds

Aromatic Substitution Reactions

Aldehydes and Ketones

Carboxylic Acids and Their Derivatives

Alpha Carbon Chemistry: Enols and Enolates

Amines

Carbohydrates

Amino Acids, Peptides, and Proteins

Lipids

Synthetic Polymers

Filters

Given the following rate law,what will happen to the rate if the concentration of MeI is doubled? Rate = k[Me₃N][MeI]

Write the rate law for the following S_N2 reaction.

Why do polar aprotic solvents favor S_N2 reactions?