Exam 1: Structure and Bonding

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Write valid Lewis (electron-dot) structures for each formula below. Show all electrons as dots and show all nonbonding electrons. -The structure of urea is shown below. Fill in any nonbonding valence electrons that are missing from the line-bond structure. Write valid Lewis (electron-dot) structures for each formula below. Show all electrons as dots and show all nonbonding electrons. -The structure of urea is shown below. Fill in any nonbonding valence electrons that are missing from the line-bond structure.

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Write valid Lewis (electron-dot) structures for each formula below. Show all electrons as dots and show all nonbonding electrons. -Write: CH3CH2OH ethanol

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Consider the two structures below to answer the following question.CH3CH2OH CH3OCH3 -The molecular orbital shown below is most likely of what type? Consider the two structures below to answer the following question.CH<sub>3</sub>CH<sub>2</sub>OH CH<sub>3</sub>OCH<sub>3</sub> -The molecular orbital shown below is most likely of what type?

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C

Consider the formation of an sp2 hybrid orbital. Which of the following is true?

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Specify the hybridization of each carbon atom of limonene, a natural product present in citrus fruits, and thujone, which is derived from wormwood, a traditional component of the notorious liquor, Absinthe. Specify the hybridization of each carbon atom of limonene, a natural product present in citrus fruits, and thujone, which is derived from wormwood, a traditional component of the notorious liquor, Absinthe.     limonene thujone Specify the hybridization of each carbon atom of limonene, a natural product present in citrus fruits, and thujone, which is derived from wormwood, a traditional component of the notorious liquor, Absinthe.     limonene thujone limonene thujone

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Draw all possible structures of CFnClm where n and m vary from 0 to 4.

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Which of the following best represents the shape of a sp3 hybrid orbital of carbon? A Which of the following best represents the shape of a sp<sup>3</sup> hybrid orbital of carbon? A   B   C   D  B Which of the following best represents the shape of a sp<sup>3</sup> hybrid orbital of carbon? A   B   C   D  C Which of the following best represents the shape of a sp<sup>3</sup> hybrid orbital of carbon? A   B   C   D  D Which of the following best represents the shape of a sp<sup>3</sup> hybrid orbital of carbon? A   B   C   D

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Propose a structure for a molecule that meets the following description. -Refer to instructions. Contains only one sp3 hybridized carbon and two sp2 hybridized carbons.

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The molecular formula C2H4O can be converted into three-line bond (Kekulé) structures that are consistent with valence rules. Which one of the following Kekulé structures is not consistent with valence rules?

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Propose a structure for a molecule that meets the following description. -Refer to instructions. Contains only two sp3 hybridized carbons and two sp hybridized carbons.

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Which of the following best represents the shape of a 2p atomic orbital of carbon? A Which of the following best represents the shape of a 2p atomic orbital of carbon? A   B   C   D  B Which of the following best represents the shape of a 2p atomic orbital of carbon? A   B   C   D  C Which of the following best represents the shape of a 2p atomic orbital of carbon? A   B   C   D  D Which of the following best represents the shape of a 2p atomic orbital of carbon? A   B   C   D

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How many total valence electrons are represented in the following electron configuration? 1s22s22px2 2py2 2pz1 or 1s22s22p5

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Draw all the lone pairs (nonbonding valence electrons) on the structure of phosgene, a poisonous gas once used as a chemical warfare agent. Draw all the lone pairs (nonbonding valence electrons) on the structure of phosgene, a poisonous gas once used as a chemical warfare agent.

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Which of the following statements is not true?

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According to atomic theory:

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In drawing the Lewis structure for an organic compound, the carbon atoms should always be shown with

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Determine the hybridization for the indicated atoms in each structure below. Determine the hybridization for the indicated atoms in each structure below.     -Refer to instructions. The hybridization of carbon atom A is _____. Determine the hybridization for the indicated atoms in each structure below.     -Refer to instructions. The hybridization of carbon atom A is _____. -Refer to instructions. The hybridization of carbon atom A is _____.

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Convert the skeletal drawing of the pharmaceutical Vioxx into a molecular formula. Convert the skeletal drawing of the pharmaceutical Vioxx into a molecular formula.

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Draw the structure for CCl2F2 using solid, wedged, and dashed lines to show the tetrahedral geometry.

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Draw two possible isomers of C6H6 in which all the carbon atoms are sp2 hybridized.

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