Exam 1: Covalent Bonding and Shapes of Molecules

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Add curved arrows, indicating the movement of electrons, to the drawings below to complete the correct mechanism for this reaction. Add curved arrows, indicating the movement of electrons, to the drawings below to complete the correct mechanism for this reaction.

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Which of the following compounds is a tertiary (3°) alcohol? Which of the following compounds is a tertiary (3°) alcohol?   I II III IV I II III IV

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The rate-determining step of the reaction represented by the following reaction energy diagram is the first step. The rate-determining step of the reaction represented by the following reaction energy diagram is the first step.

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______________ are the basis for compound nomenclature.

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Which point on the energy diagram represents the intermediate? Which point on the energy diagram represents the intermediate?

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The following alkenes are listed in decreasing order of heat of hydrogenation (most negative first). The following alkenes are listed in decreasing order of heat of hydrogenation (most negative first).

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Which is the product of the reaction of 1-methylcyclohexene with H2O/H2SO4? Which is the product of the reaction of 1-methylcyclohexene with H<sub>2</sub>O/H<sub>2</sub>SO<sub>4</sub>?

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An neutral atom that has gained electrons is called an anion.

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Draw the intermediate of the following reaction. Draw the intermediate of the following reaction.

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Which reagents react with an alkene by syn addition? i. Cl2 II. Br2 III. H2/Pt IV. BH3, followed by H2O2/NaOH/H2O

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Which is the intermediate formed in the reaction of propene with HBr? Which is the intermediate formed in the reaction of propene with HBr?

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Orbitals make up the majority of the mass of an atom.

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Which statements describes an intermediate?

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Atoms of the group 7A elements react by losing an electron to achieve a noble gas configuration.

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Which functional groups have correct Lewis structures? Which functional groups have correct Lewis structures?

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Which of the three molecules testosterone, methadone and hydrocodone contains an amine? Which of the three molecules testosterone, methadone and hydrocodone contains an amine?

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Arrange these carbocations in order of increasing stability (least to most). Arrange these carbocations in order of increasing stability (least to most).

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The activation energies of the reaction represented by the following reaction energy diagram are noted as I and II. The activation energies of the reaction represented by the following reaction energy diagram are noted as I and II.

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Which of the following are pairs of contributing structures? Which of the following are pairs of contributing structures?

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Hydrohalogenation, hydration, and bromination reactions proceed through a carbocation intermediate.

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