Exam 2: Polar Covalent Bonds: Acids and Bases

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Rank the following in order of decreasing importance as a contributing resonance structure to the molecular structure of acetone,CH3COCH3 (more important > less important). Rank the following in order of decreasing importance as a contributing resonance structure to the molecular structure of acetone,CH<sub>3</sub>COCH<sub>3</sub> (more important > less important).

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Instructions: Consider the molecules below to answer the following question. Instructions: Consider the molecules below to answer the following question.    -Refer to instructions.Which of the following is an accurate description of the noncovalent interactions between like molecules? -Refer to instructions.Which of the following is an accurate description of the noncovalent interactions between like molecules?

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Write an equation for the reaction of boron trifluoride,an important reagent in organic chemistry,with trimethylamine.Represent the movement of electrons with a curved arrow,and show the formal charges on the atoms in the product.Write an equation for the reaction of boron trifluoride,an important reagent in organic chemistry,with trimethylamine.Represent the movement of electrons with a curved arrow,and show the formal charges on the atoms in the product.

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Instructions: Label the acid and base in each reaction below. -Label:Instructions: Label the acid and base in each reaction below. -Label:

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Instructions: Refer to the following equation to answer the question(s)below. Instructions: Refer to the following equation to answer the question(s)below.     -Refer to instructions.The strongest Brønsted-Lowry base in the equation is indicated by letter _____. -Refer to instructions.The strongest Brønsted-Lowry base in the equation is indicated by letter _____.

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Instructions: Consider the reaction below to answer the following question. Instructions: Consider the reaction below to answer the following question.    -Refer to instructions.Using the curved arrow formalism,show the flow of electrons for this reaction. -Refer to instructions.Using the curved arrow formalism,show the flow of electrons for this reaction.

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Identify the reactants and product in the reaction below as acids or bases and specify whether they are Lewis and/or Brønsted-Lowry. Identify the reactants and product in the reaction below as acids or bases and specify whether they are Lewis and/or Brønsted-Lowry.

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Draw a Lewis structure for each of the following. Draw a Lewis structure for each of the following.

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Write an equation for the reaction of the alkaloid ephedrine with a proton,showing the structure of its conjugate base.Write an equation for the reaction of the alkaloid ephedrine with a proton,showing the structure of its conjugate base.

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Which of the following statements is not true regarding resonance structures?

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Instructions: Refer to the following equation to answer the question(s)below. Instructions: Refer to the following equation to answer the question(s)below.    -Refer to instructions.Will this reaction take place as written in the forward direction? Explain. -Refer to instructions.Will this reaction take place as written in the forward direction? Explain.

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Consider the structure of acetic acid shown below. Consider the structure of acetic acid shown below.   In the electrostatic potential map of acetic acid,in which of the following bonds would the terminal atom appear as the deepest shade of red? In the electrostatic potential map of acetic acid,in which of the following bonds would the terminal atom appear as the deepest shade of red?

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Guanidine is a fairly strong amine base that is attached to the amino acid arginine.Draw three resonance forms for the conjugate acid of guanidine. Guanidine is a fairly strong amine base that is attached to the amino acid arginine.Draw three resonance forms for the conjugate acid of guanidine.

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The following shows an intermediate used in a Grignard synthesis.Which atom will inductively donate electrons in this species? The following shows an intermediate used in a Grignard synthesis.Which atom will inductively donate electrons in this species?

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Use the curved arrow method to show the electron movement,and label the acid,base,conjugate acid,and conjugate base.Use the curved arrow method to show the electron movement,and label the acid,base,conjugate acid,and conjugate base.

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