Exam 17: Additional Aspects of Aqueous Equilibria

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How many milliliters of 0.120 M NaOH are required to titrate 50.0 mL of 0.0998 M hypochlorous acid to the equivalence point? The Ka of hypochlorous acid is 3.0 × 10-8.

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A solution is prepared by dissolving 0.23 mol of hypochlorous acid and 0.27 mol of sodium hypochlorite in water sufficient to yield 1.00 L of solution. The addition of 0.05 mol of HCl to this buffer solution causes the pH to drop slightly. The pH does not decrease drastically because the HCl reacts with the ________ present in the buffer solution. The Ka of hypochlorous acid is 1.36 × 10-3.

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For which salt should the aqueous solubility be most sensitive to pH?

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The Kb of ammonia is 1.76 × 10-5. The pH of a buffer prepared by combining 50.0 mL of 1.00 M ammonia and 45.0 mL of 1.00 M ammonium nitrate is ________.

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The primary buffer system that controls the pH of the blood is the ________ buffer system.

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Suppose you have just added 200.0 ml of a solution containing 0.5000 moles of acetic acid per liter to 100.0 ml of 0.5000 M NaOH. What is the final pH? The Ka of acetic acid is 1.77 × 10-5.

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A 25.0 mL sample of 0.150 M benzoic acid is titrated with a 0.150 M NaOH solution. What is the pH at the equivalence point? The Ka of benzoic acid is 4.50 × 10-4.

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A 25.0-mL sample of 0.150 M hypochlorous acid is titrated with a 0.150 M NaOH solution. What is the pH after 13.3 mL of base is added? The Ka of hypochlorous acid is 3.0 × 10-8.

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An assembly of a metal ion and the Lewis bases bonded to it is called a(n)________.

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The addition of hydrochloric acid and ________ to water produces a buffer solution.

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200.0 ml of a solution containing 0.5000 moles of acetic acid per liter is added to 200.0 ml of 0.5000 M NaOH. What is the final pH? The Ka of acetic acid is 1.77 × 10-5.

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A buffer solution with a pH of 4.40 is prepared with 0.78 M Na C2H3O2 and ________ M HC2H3O2. The Ka of HC2H3O2 is 1.8 × 10-5.

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Calculate the pH of a buffer that contains 0.270 M hydrofluoric acid (HF)and 0.180 M cesium fluoride (CsF). The Ka of hydrofluoric acid is 6.80 × 10-4.

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In which one of the following solutions is silver chloride the most soluble?

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Calculate the pH of a solution prepared by dissolving 0.150 mol of acetic acid and 0.300 mol of sodium acetate in water sufficient to yield 1.00 L of solution. The Ka of acetic acid is 1.76 × 10-5.

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Calculate the pH of a solution that is 0.278 M in sodium formate (NaHCO2)and 0.222 M in formic acid (HCO2H). The Ka of formic acid is 1.77 × 10-4.

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Calculate the pH of a solution prepared by dissolving 0.850 mol of NH3 and 0.300 mol of NH4Cl in water sufficient to yield 1.00 L of solution. The Kb of ammonia is 1.77 × 10-5.

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The solubility product of a compound is numerically equal to the product of the concentration of the ions involved in the equilibrium, each multiplied by its coefficient in the equilibrium reaction.

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In which of the following aqueous solutions would you expect CuBr to have the highest solubility?

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What is the pH of a buffer solution that is 0.266 M in lactic acid and 0.111 M in sodium lactate? The Ka of lactic acid is 1.4 × 10-4.

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