Exam 17: Additional Aspects of Aqueous Equilibria

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A 25.0-mL sample of 0.150 M hydrocyanic acid is titrated with a 0.150 M NaOH solution. What is the pH before any base is added? The Ka of hydrocyanic acid is 4.9 × 10-10.

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________ analysis determines only the presence or absence of a particular metal ion, whereas ________ analysis determines how much of a given substance is present.

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A buffer solution with a pH of 4.63 is prepared with 0.14 M formic acid and ________ M sodium formate. The Ka of formic acid is 1.8 × 10-4.

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A 25.0 mL sample of 0.723 M HClO4 is titrated with a 0.273 M KOH solution. The H3O+ concentration after the addition of 0.00 mL of KOH is ________ M.

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Which of the following could be added to a solution of acetic acid to prepare a buffer?

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In general, the solubility of a slightly soluble salt is ________ by the presence of a second solute that furnishes a common ion.

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Calculate the pH of a solution that is 0.322 M in nitrous acid (HNO2)and 0.178 M in potassium nitrite (KNO2). The acid dissociation constant of nitrous acid is 4.50 × 10-4.

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Metal oxides and hydroxides that are relatively insoluble in neutral water, but are soluble in both strongly acidic and strongly basic solutions are said to be ________.

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Determine the Ksp for magnesium hydroxide (Mg(OH)2)where the solubility of Mg(OH)2 is 1.4 × 10-4 M.

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  -A 25.0 mL sample of a solution of an unknown compound is titrated with a 0.115 M NaOH solution. The titration curve above was obtained. The unknown compound is ________. -A 25.0 mL sample of a solution of an unknown compound is titrated with a 0.115 M NaOH solution. The titration curve above was obtained. The unknown compound is ________.

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A solution is prepared by dissolving 0.23 mol of benzoic acid and 0.27 mol of sodium benzoate in water sufficient to yield 1.00 L of solution.The addition of 0.05 mol of NaOH to this buffer solution causes the pH to increase slightly. The pH does not increase drastically because the NaOH reacts with the ________ present in the buffer solution. The Ka of benzoic acid is 6.3 × 10-5.

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What is the molar solubility of calcium carbonate ( CaCO3 )in water? The solubility-product constant for CaCO3 is 4.5 × 10-9 at 25 °C.

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Calculate the percent ionization of nitrous acid in a solution that is 0.241 M in nitrous acid (HNO2)and 0.195 M in potassium nitrite (KNO2). The acid dissociation constant of nitrous acid is 4.50 × 10-4.

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Which one of the following will cause hemoglobin to release oxygen?

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How many milliliters of 0.0839 M NaOH are required to titrate 25.0 mL of 0.0990 M HBr to the equivalence point?

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Although CaCO3 has a relatively small solubility product, it is quite soluble in the presence of ________.

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The Ka of benzoic acid is 6.30 × 10-5. The pH of a buffer prepared by combining 50.0 mL of 1.00 M potassium benzoate and 50.0 mL of 1.00 M benzoic acid is ________.

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A buffer solution with a pH of 4.78 is prepared with ________ M formic acid and 0.90 M sodium formate. The Ka of formic acid is 1.8 × 10-4.

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Why does fluoride treatment render teeth more resistant to decay?

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The pH of a solution prepared by dissolving 0.350 mol of solid methylamine hydrochloride (CH3NH3Cl)in 1.00 L of 1.10 M methylamine (CH3NH2)is ________. The Kb for methylamine is 4.40 × 10-4. (Assume the final volume is 1.00 L.)

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