Exam 13: When Reactants Turn Into Products

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Consider the reaction A + B → Products. If the rate equation is Rate = -k[A]3[B]0 the order of the reaction with respect to A, B, and the total order respectively is ________.

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Which of the following does not influence the speed of a chemical reaction?

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  -In the diagram above, the two containers shown (Box A and BoxB)have exactly the same size (volume), are held at the same temperature, and contain reactant molecules (dots). In which box will the rate of reaction be faster? -In the diagram above, the two containers shown (Box A and BoxB)have exactly the same size (volume), are held at the same temperature, and contain reactant molecules (dots). In which box will the rate of reaction be faster?

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A reaction follows the rate law: Rate = -k[A]2[B]1. The overall order is ________.

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A reaction follows the rate law: Rate = -k[A]3[B]-1. The overall order is ________.

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Knowing the mechanism of a reaction is advantageous because one may influence its rate to make the reaction useful.

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Which of the following is not true when the temperature of the reaction mixture is decreased?

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Calculate a value for ΔErxn for a chemical reaction, if the reactants have an energy of +300 kJ/mol and the products have an energy of +100 kJ/mol. Is this reaction exothermic or endothermic?

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The difference in energy between the reactants and products in a chemical reaction is called ________.

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Calculate a value for ΔErxn for a chemical reaction if the reactants have an energy of -400 kJ/mol and the products have an energy of +100 kJ/mol. Is this reaction exothermic or endothermic? Calculate a value for ΔE<sub>rxn</sub> for a chemical reaction if the reactants have an energy of -400 kJ/mol and the products have an energy of +100 kJ/mol. Is this reaction exothermic or endothermic?   a)Estimate the value for the activation energy for this reaction. b)Calculate ΔErxn. c)Is this reaction exothermic or endothermic?  a)Estimate the value for the activation energy for this reaction. b)Calculate ΔErxn. c)Is this reaction exothermic or endothermic?

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In the reaction where Rate = [A]2, the rate is second order with respect to the reactant and second order overall.

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The rate of reaction: A (g)+ 3B (g)→ C (g)+ 2D (g)is Rate = -k[A][B]3. If the concentration of B is doubled while that of A is unchanged, the rate will ________.

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A catalyst lowers the activation energy for a chemical reaction.

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It is possible to determine a given reaction's mechanism without performing any experiments of any kind.

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Use the table below to answer the question that follows: Use the table below to answer the question that follows:   -The above data were obtained in a kinetic study of the reaction. a)Determine the orders x and y, assuming that rate = k[NO]<sup>x</sup>[Cl<sub>2</sub>]<sup>y</sup>. b)Determine the value for the rate constant, k, in Experiment 2. c)Determine the overall order of this reaction. -The above data were obtained in a kinetic study of the reaction. a)Determine the orders x and y, assuming that rate = k[NO]x[Cl2]y. b)Determine the value for the rate constant, k, in Experiment 2. c)Determine the overall order of this reaction.

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Which of the following is true about enzymes?

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For an endothermic reaction, the value for ΔErxn is a negative number.

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The rate constant is dependant on the activation energy and reactant orientation.

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Match the rate of each reaction in the questions with the overall order that appears in the list below.
Rate = -k[A]²[B]²
2
Rate = -k[A][B]-₁
4
Rate = -k[A]²[B]-¹
1
Correct Answer:
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Responses:
Rate = -k[A]²[B]²
2
Rate = -k[A][B]-₁
4
Rate = -k[A]²[B]-¹
1
Rate = -k[A][B]
0
Rate = -k[A]³[B]⁰
3
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Which of the following is true about a catalyst?

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