Exam 7: Acids and Bases

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The following three equations represent equilibria that lie far to the right. HNO3(aq) + CN-(aq) The following three equations represent equilibria that lie far to the right. HNO<sub>3</sub>(aq) + CN<sup>-</sup>(aq)   HCN(aq) + NO<sub>3</sub><sup>-</sup>(aq) HCN(aq) + OH<sup>-</sup>(aq)   H<sub>2</sub>O(l) + CN<sup>-</sup>(aq) H<sub>2</sub>O(l) + CH<sub>3</sub>O<sup>-</sup>(aq)   CH<sub>3</sub>OH(aq) + OH<sup>-</sup>(aq) -Identify the strongest acid. HCN(aq) + NO3-(aq) HCN(aq) + OH-(aq) The following three equations represent equilibria that lie far to the right. HNO<sub>3</sub>(aq) + CN<sup>-</sup>(aq)   HCN(aq) + NO<sub>3</sub><sup>-</sup>(aq) HCN(aq) + OH<sup>-</sup>(aq)   H<sub>2</sub>O(l) + CN<sup>-</sup>(aq) H<sub>2</sub>O(l) + CH<sub>3</sub>O<sup>-</sup>(aq)   CH<sub>3</sub>OH(aq) + OH<sup>-</sup>(aq) -Identify the strongest acid. H2O(l) + CN-(aq) H2O(l) + CH3O-(aq) The following three equations represent equilibria that lie far to the right. HNO<sub>3</sub>(aq) + CN<sup>-</sup>(aq)   HCN(aq) + NO<sub>3</sub><sup>-</sup>(aq) HCN(aq) + OH<sup>-</sup>(aq)   H<sub>2</sub>O(l) + CN<sup>-</sup>(aq) H<sub>2</sub>O(l) + CH<sub>3</sub>O<sup>-</sup>(aq)   CH<sub>3</sub>OH(aq) + OH<sup>-</sup>(aq) -Identify the strongest acid. CH3OH(aq) + OH-(aq) -Identify the strongest acid.

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The dihydrogenphosphate ion, H2PO4-, has both a conjugate acid and a conjugate base. These are, respectively,

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If the following substance is dissolved in pure water, will the solution be acidic, neutral, or basic? solid potassium chloride (KCl)

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Which of the following is a conjugate acid-base pair?

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Identify the Brønsted acids and bases in the following equation (A = Brønsted acid, B = Brønsted base). HPO42- + HSO4- Identify the Brønsted acids and bases in the following equation (A = Brønsted acid, B = Brønsted base). HPO<sub>4</sub><sup>2</sup><sup>-</sup> + HSO<sub>4</sub><sup>-</sup>   H<sub>2</sub>PO<sub>4</sub><sup>-</sup> + SO<sub>4</sub><sup>2</sup><sup>-</sup> H2PO4- + SO42-

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Calculate the [H+] in a 2.0 10-6 M solution of NaC2H3O2.(Ka for HC2H3O2 = 1.8 10-5)

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The conjugate acid and conjugate base of bicarbonate ion, HCO3-, are, respectively,

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How many moles of benzoic acid, a monoprotic acid with Ka = 6.4 10-5, must be dissolved in 500. mL of H2O to produce a solution with pH = 2.50?

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Which of the following statements is true for polyprotic acids?

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The pH of a solution is raised from 3 to 5. Which statement is false?

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The pH of a 0.013 M weak acid solution is 5.27. Calculate Ka for this acid.

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Which of the following represents a conjugate acid-base pair?

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The salt BX, when dissolved in water, produces an acidic solution. Which of the following could be true?

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The pKa of HOCl is 7.5. Calculate the pH of a 0.5 M solution of HOCl.

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Calculate the pH of a solution made by mixing equal volumes of a solution of NaOH with a pH of 11.40 and a solution of KOH with a pH of 10.30. (Assume the volumes are additive.)

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Determine the pH of a solution made by adding 1.0 * 10-7 mol of HCl to 1.0 L of solution.

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In pure liquid ammonia, the equilibrium concentrations of both NH4+ and NH2- are 3 10-14 M. Which of the following equations always holds for liquid ammonia solutions?

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Calculate [OH-] in a 4.0 10-8 M solution of NaOH.

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A 0.050 M aqueous solution of a weak monoprotic acid is 1.2% ionized at equilibrium at 25° C. Calculate Ka for this acid.

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Find the pH of a solution at 25°C in which [OH-] = 2.5 10-9 M.

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