Exam 7: Acids and Bases

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The pH of a strong acid solution is always lower than the pH of a weak acid solution. If this is true, explain why and include an example with calculations. If it is false, explain why and include a counterexample with calculations.

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The pH of a solution made of 0.100 mol of a weak monoprotic acid HA in 1.000 L of solution is 1.470. Calculate Ka for this acid.

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Calculate the pH of a 0.005 M solution of potassium oxide, K2O.

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If the following substance is dissolved in pure water, will the solution be acidic, neutral, or basic? solid sodium bicarbonate (NaHCO3)

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If the following substance is dissolved in pure water, will the solution be acidic, neutral, or basic? solid ammonium fluoride (NH4F) For NH3, Kb = 1.8 10-5; for HF, Ka = 7.2 10-4.

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How much water should be added to 10.0 mL of 12.0 M HCl so that it has the same pH as 0.90 M acetic acid (Ka = 1.8 10-5)? (Assume the volumes are additive.)

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Calculate the pH of a 2.0 10-5 M solution of HOC6H5. (Ka = 1.6 10-10)

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Calculate the pOH of a 0.70 M solution of acetic acid (Ka = 1.8 10-5) at 25°C.

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Which of the following reactions is associated with the definition of Ka?

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For the equilibrium that exists in an aqueous solution of nitrous acid (HNO2, a weak acid), the equilibrium constant expression is

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HOAc Ka = 1.8 10-5 H2CO3 Ka1 = 4.3 10-7, Ka2 = 5.6 10-11 Which of the following 0.01 M solutions has the highest pH?

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Calculate the pH of a 0.040 M perchloric acid (HClO4) solution.

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Calculate [H+] in a 0.012 M solution of HCN, Ka = 6.2 10-10.

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Which of the following species is not amphoteric?

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The conjugate base of a weak acid is

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Calculate [H+] in a 1.2 10-5 M solution of NH4Cl. (Kb for NH3 = 1.8 10-5)

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The following three equations represent equilibria that lie far to the right. HNO3(aq) + CN-(aq) The following three equations represent equilibria that lie far to the right. HNO<sub>3</sub>(aq) + CN<sup>-</sup>(aq)   HCN(aq) + NO<sub>3</sub><sup>-</sup>(aq) HCN(aq) + OH<sup>-</sup>(aq)   H<sub>2</sub>O(l) + CN<sup>-</sup>(aq) H<sub>2</sub>O(l) + CH<sub>3</sub>O<sup>-</sup>(aq)   CH<sub>3</sub>OH(aq) + OH<sup>-</sup>(aq) -Identify the strongest base. HCN(aq) + NO3-(aq) HCN(aq) + OH-(aq) The following three equations represent equilibria that lie far to the right. HNO<sub>3</sub>(aq) + CN<sup>-</sup>(aq)   HCN(aq) + NO<sub>3</sub><sup>-</sup>(aq) HCN(aq) + OH<sup>-</sup>(aq)   H<sub>2</sub>O(l) + CN<sup>-</sup>(aq) H<sub>2</sub>O(l) + CH<sub>3</sub>O<sup>-</sup>(aq)   CH<sub>3</sub>OH(aq) + OH<sup>-</sup>(aq) -Identify the strongest base. H2O(l) + CN-(aq) H2O(l) + CH3O-(aq) The following three equations represent equilibria that lie far to the right. HNO<sub>3</sub>(aq) + CN<sup>-</sup>(aq)   HCN(aq) + NO<sub>3</sub><sup>-</sup>(aq) HCN(aq) + OH<sup>-</sup>(aq)   H<sub>2</sub>O(l) + CN<sup>-</sup>(aq) H<sub>2</sub>O(l) + CH<sub>3</sub>O<sup>-</sup>(aq)   CH<sub>3</sub>OH(aq) + OH<sup>-</sup>(aq) -Identify the strongest base. CH3OH(aq) + OH-(aq) -Identify the strongest base.

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Arrange the following 0.10 M solutions from lowest to highest pH: NaF, NaC2H3O2, C5H5NHCl, KOH, HCN. (Ka for HCN is 6.2 10-10; Ka for HF is 7.2 10-4; Ka for HC2H3O2 is 1.8 10-5; and Kb for C5H5N is 1.7 10-9)

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If the following substance is dissolved in pure water, will the solution be acidic, neutral, or basic? solid sodium cyanide (NaCN)

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