Exam 28: Quantum Mechanics of Atoms

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If the uncertainty in the position of a proton is 0.053 nm0.053 \mathrm {~nm} , what is the uncertainty in its speed? ( h=h = 6.626×1034 Js,mproton =1.67×1027 kg6.626 \times 10 ^ { - 34 } \mathrm {~J} \cdot \mathrm { s } , m _ { \text {proton } } = 1.67 \times 10 ^ { - 27 } \mathrm {~kg} )

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An atom has completely filled inner shells and a single valence electron in an excited p state. The filled inner shells have an orbital momentum equal to zero. What is the magnitude of the orbital angular momentum of the atom?

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The excited state of a certain atom is 3.2eV±0.21eV.(h=6.626×1034 Js,1eV=1.60×3.2 \mathrm { eV } \pm 0.21 \mathrm { eV } . \left( h = 6.626 \times 10 ^ { - 34 } \mathrm {~J} \cdot \mathrm { s } , 1 \mathrm { eV } = 1.60 \times \right. 1019 J10 ^ { - 19 } \mathrm {~J} ) (a) What is the average lifetime of this state, in femtoseconds? (b) If the excited energy were doubled (to 6.4eV±0.21eV6.4 \mathrm { eV } \pm 0.21 \mathrm { eV } ), how would the lifetime be affected?

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(a) 3.1fs3.1 \mathrm { fs }
(b) unchanged since the uncertainty is still ±0.21eV\pm 0.21 \mathrm { eV }

The orbital angular momentum quantum number ʆ can have any integer value ranging from

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If n=5n = 5 , which one of the following is not an allowed magnetic quantum number m1?

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Consider the n=10n = 10 shell. (a) What is the largest value of the angular momentum quantum number, ll , in this shell? (b) How many electrons can be placed in this shell?

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In its ground state, the quantum numbers (n,l,m1,mS)\left( n , l , m _ { 1 } , m _ { S } \right) for hydrogen are, respectively,

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An atom has completely filled inner shells and a single valence electron in an excited pp state. The filled inner shells have an orbital momentum equal to zero. When a magnetic field is applied, what are the possible angles between the magnetic field and the orbital angular momentum?

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If the maximum possible accuracy in measuring the velocity of a particle increases, the maximum possible accuracy in measuring its position will

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The elements in the periodic table that have completely filled shells or subshells are referred to as

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Consider ground-state helium having two electrons in orbit. If one of the electrons has quantum numbers (n,l,m1,ms)\left( n , \ell l , m _ { 1 } , m _ { s } \right) of 1,0,0,1/21,0,0 , - 1 / 2 respectively, the quantum numbers for the other electron will be

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How many 2d electron states can an atom have?

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A laser produces a beam of 4000nm4000 - \mathrm { nm } light. A shutter allows a pulse of light, 30ps30 \mathrm { ps } in duration, to pass through. What is the uncertainty in the energy of a photon in the pulse? (1eV=1.60×1019 J\left( 1 \mathrm { eV } = 1.60 \times 10 ^ { - 19 } \mathrm {~J} \right. , h=6.626×1034 Jsh = 6.626 \times 10 ^ { - 34 } \mathrm {~J} \cdot \mathrm { s } )

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If the maximum possible accuracy in measuring the lifetime of a particle increases, the maximum possible accuracy in measuring its energy will

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How many unique quantum states correspond to the lowest possible energy level of an electron in the hydrogen atom?

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In an excited hydrogen atom, the electron is in the 4d4 d state. If this atom is in an external magnetic field, what are the smallest and largest possible angles between the orbital angular momentum and the direction of the magnetic field (or any other direction, for that matter)?

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If the maximum possible accuracy in measuring the position of a particle increases, the maximum possible accuracy in measuring its velocity will

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An unstable particle produced in a high-energy collision is measured to have an energy of 483MeV483 \mathrm { MeV } and an uncertainty in energy of 29keV29 \mathrm { keV } . Use the Heisenberg uncertainty principle to estimate the lifetime of this particle. (h=6.626×1034 Js,1eV=1.60×1019)\left( h = 6.626 \times 10 ^ { - 34 } \mathrm {~J} \cdot \mathrm { s } , 1 \mathrm { eV } = 1.60 \times 10 ^ { - 19 } \right)

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How many electrons will fit into a 4f subshell?

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If the maximum possible accuracy in measuring the energy of a particle increases, the maximum possible accuracy in measuring its lifetime will

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