Exam 27: Early Quantum Theory and Models of the Atom

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A monochromatic light beam is incident on the surface of a metal having a work function of 2.502.50 eV\mathrm { eV } . If a 1.0V1.0 - \mathrm { V } stopping potential is required to make the electron current zero, what is the wavelength of light? (c=3.00×108 m/s,h=6.626×1034 Js,1eV=1.60×1019 J)\left( c = 3.00 \times 10 ^ { 8 } \mathrm {~m} / \mathrm { s } , h = 6.626 \times 10 ^ { - 34 } \mathrm {~J} \cdot \mathrm { s } , 1 \mathrm { eV } = 1.60 \times 10 ^ { - 19 } \mathrm {~J} \right)

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What is the value of n in the Balmer series for which the wavelength is 410.2 nm.

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The figure shows part of the energy level diagram of a certain atom. The energy spacing between levels 1 and 2 is twice that between 2 and 3 . If an electron makes a transition from level 3 to level 2 , the radiation of wavelength λ\lambda is emitted. What possible radiation wavelengths might be produced by other transitions between the three energy levels?

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What is the wavelength of a photon having the same momentum as an electron that is traveling at 7.5 km/s7.5 \mathrm {~km} / \mathrm { s } ? (h=6.626×1034 Js,melectron =9.11×1031 kg)\left( h = 6.626 \times 10 ^ { - 34 } \mathrm {~J} \cdot \mathrm { s } , m _ { \text {electron } } = 9.11 \times 10 ^ { - 31 } \mathrm {~kg} \right)

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In a transition from one vibrational state to another, a molecule emits a photon of wavelength 5.565.56 μm\mu \mathrm { m } . What is the energy difference between these two states? (c=3.00×108 m/s,h=6.626×1034 J\left( c = 3.00 \times 10 ^ { 8 } \mathrm {~m} / \mathrm { s } , h = 6.626 \times 10 ^ { - 34 } \mathrm {~J} \right. s,1eV=1.60×1019 J\cdot \mathrm { s } , 1 \mathrm { eV } = 1.60 \times 10 ^ { - 19 } \mathrm {~J} )

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A hydrogen atom is excited to the n=11n = 11 level. Its decay to the n=7n = 7 level is detected in a photographic plate. What is the wavelength of the light photographed? (c=3.00×108 m/s,1eV=\left( c = 3.00 \times 10 ^ { 8 } \mathrm {~m} / \mathrm { s } , 1 \mathrm { eV } = \right. 1.60×1019 J,h=6.626×1034 Js)\left. 1.60 \times 10 ^ { - 19 } \mathrm {~J} , h = 6.626 \times 10 ^ { - 34 } \mathrm {~J} \cdot \mathrm { s } \right)

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What frequency must a photon have to raise an electron in a hydrogen atom from the n=2n = 2 to the nn =4= 4 state? (h=6.626×1034 Js,1eV=1.60×1019 J)\left( h = 6.626 \times 10 ^ { - 34 } \mathrm {~J} \cdot \mathrm { s } , 1 \mathrm { eV } = 1.60 \times 10 ^ { - 19 } \mathrm {~J} \right)

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What are the wavelength and the corresponding photon energy (in electron-volts) of the primary light emitted by an ideal blackbody at each of the following temperatures? (c=( c = 3.00×108 m/s,h=6.626×1034 Js,1eV=1.60×1019 J3.00 \times 10 ^ { 8 } \mathrm {~m} / \mathrm { s } , h = 6.626 \times 10 ^ { - 34 } \mathrm {~J} \cdot \mathrm { s } , 1 \mathrm { eV } = 1.60 \times 10 ^ { - 19 } \mathrm {~J} , and the constant in Wein's law is 0.00290 mK0.00290 \mathrm {~m} \cdot \mathrm { K } ) (a) 400C400 ^ { \circ } \mathrm { C } ? (b) 800C800 ^ { \circ } \mathrm { C } ? (c) 1200C1200 ^ { \circ } \mathrm { C } ?

(Short Answer)
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A hydrogen atom makes a downward transition from the n=15n = 15 state to the n=5n = 5 state. Find the wavelength of the emitted photon. (c=3.00×108 m/s,1eV=1.60×1019 J,h=6.626×1034 Js\left( c = 3.00 \times 10 ^ { 8 } \mathrm {~m} / \mathrm { s } , 1 \mathrm { eV } = 1.60 \times 10 ^ { - 19 } \mathrm {~J} , h = 6.626 \times 10 ^ { - 34 } \mathrm {~J} \cdot \mathrm { s } \right. )

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Calculate the orbital Bohr radius of the n=2n = 2 excited state in a hydrogen atom. (r1=0.0529 nm)\left( r _ { 1 } = 0.0529 \mathrm {~nm} \right)

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A neutral boron atom has 5 electrons, but in this case all but one of its electrons have been knocked off. How much energy (in electron-volts) is needed to remove the last electron?

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What would be the de Broglie wavelength for 1g1 - \mathrm { g } object moving at the earth's escape speed 25,000 mph (about 11 km/s)11 \mathrm {~km} / \mathrm { s } ) ? (h=6.626×1034 Js)\left( h = 6.626 \times 10 ^ { - 34 } \mathrm {~J} \cdot \mathrm { s } \right)

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What is the surface temperature of a star, if its radiation peak occurs at a frequency of 1.06×10151.06 \times 10^{15} Hz\mathrm { Hz } ? (c=3.00×108 m/s\left( c = 3.00 \times 10 ^ { 8 } \mathrm {~m} / \mathrm { s } \right. , and the constant in Wien's law is 0.00290 mK)\left. 0.00290 \mathrm {~m} \cdot \mathrm { K } \right)

(Multiple Choice)
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A proton has a speed of 7.2×104 m/s7.2 \times 10 ^ { 4 } \mathrm {~m} / \mathrm { s } . What is the energy of a photon that has the same wavelength as the de Broglie wavelength of this proton? (melectron =9.11×1031 kg,c=3.00×\left( m _ { \text {electron } } = 9.11 \times 10 ^ { - 31 } \mathrm {~kg} , c = 3.00 \times \right. 108 m/s,h=6.626×1034 Js)\left. 10 ^ { 8 } \mathrm {~m} / \mathrm { s } , h = 6.626 \times 10 ^ { - 34 } \mathrm {~J} \cdot \mathrm { s } \right)

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Protons are being accelerated in a particle accelerator. When the speed of the protons is doubled, their de Broglie wavelength will

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What is the wavelength of the matter wave associated with a 0.50kg0.50 - \mathrm { kg } ball moving at 25 m/s25 \mathrm {~m} / \mathrm { s } ? (h=( h = 6.626×1034 Js)\left. 6.626 \times 10 ^ { - 34 } \mathrm {~J} \cdot \mathrm { s } \right)

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A helium-neon laser emits light at 632.8 nm632.8 \mathrm {~nm} . If the laser emits 1.82×10171.82 \times 1017 photons/second, what is its power output in mW?(c=3.00×108 m/s,h=6.626×1034 Js)\mathrm { mW } ? \left( c = 3.00 \times 10 ^ { 8 } \mathrm {~m} / \mathrm { s } , h = 6.626 \times 10 ^ { - 34 } \mathrm {~J} \cdot \mathrm { s } \right)

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A hydrogen atom is excited to the n=9n = 9 level. Its decay to the n=6n = 6 level detected in a photographic plate. What is the frequency of the light photographed? (1eV=1.60×1019 J,h=6.626×1034 J\left( 1 \mathrm { eV } = 1.60 \times 10 ^ { - 19 } \mathrm {~J} , h = 6.626 \times 10 ^ { - 34 } \mathrm {~J} \right. . s)

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When light of wavelength 350 nm350 \mathrm {~nm} is incident on a metal surface, the stopping potential of the photoelectrons is 0.500 V0.500 \mathrm {~V} . What is the threshold (cutoff) frequency of this metal? (c=3.00×108\left( c = 3.00 \times 10 ^ { 8 } \right. m/s,h=6.626×1034 Js,1eV=1.60×1019 J\mathrm { m } / \mathrm { s } , h = 6.626 \times 10 ^ { - 34 } \mathrm {~J} \cdot \mathrm { s } , 1 \mathrm { eV } = 1.60 \times 10 ^ { - 19 } \mathrm {~J} )

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When a metal is illuminated by light, photoelectrons are observed provided that the wavelength of the light is less than 520 nm520 \mathrm {~nm} . What is the metal's work function? ( c=3.00×108 m/s,h=6.626×c = 3.00 \times 10 ^ { 8 } \mathrm {~m} / \mathrm { s } , h = 6.626 \times 1034 Js,1eV=1.60×1019 J10 ^ { - 34 } \mathrm {~J} \cdot \mathrm { s } , 1 \mathrm { eV } = 1.60 \times 10 ^ { - 19 } \mathrm {~J} )

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