Exam 20: Kinetic Theory of Gases

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If CP for an ideal gas is 35.4 J/mol⋅K, which of the following is CV for this gas?

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D

The internal energy of n moles of an ideal gas depends on

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If the rms speed of helium atoms is vrms,He at temperature T, what is the rms speed of CO2 at the same temperature?

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Two tanks of gas, one of hydrogen, H2, and one of helium, He, contain equal masses of gas. The gram-molecular mass of He is twice that of H2. Both tanks of gas are at the same temperature, 293 K. Which statement(s) below is(are) correct when we ignore vibrational motion?

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During the volcanic eruption of Mt. Pelee in 1902, an incredibly hot "burning cloud" rolled down the mountain and incinerated the town of Saint-Pierre. From the damage done, the temperature in the cloud was estimated at 700°C. If the air temperature was 20°C and a mole of air is 29 grams, estimate the molecular weight of the gas in the "burning cloud" that made it heavier than the surrounding air. (As a follow-on, estimate the most probable composition of the cloud. Some typical volcanic gases are H2S, SO2, H2SO4, CO2, NO.)

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Two tanks of gas, one of hydrogen, H2, and one of helium, He, contain equal numbers of moles of gas. The gram-molecular mass of He is twice that of H2. Both tanks of gas are at the same temperature, 293 K. Which statement(s) below is(are) correct when we ignore vibrational motion?

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According to kinetic theory, a typical gas molecule in thermal equilibrium at room temperature has a kinetic energy K = 6.00 × 10−21 J, regardless of mass. Estimate the speed at room temperature of a hydrogen molecule H2 (m = 3.34 × 10−27 kg) and a xenon atom (m = 2.00 × 10−25 kg). [kB = 1.38 × 10−23 J/K]

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One mole of hydrogen, one mole of nitrogen and one mole of oxygen are held in a 22.4 × 103 cm3 enclosed vessel at 20°C. The pressure in the vessel, in N/m2, is

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During an adiabatic compression, a volume of air decreases to 1/4 its original size. Calculate its final pressure if its original pressure was 1 atm. (Assume the air behaves like an ideal gas with γ = 1.4.)

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When we consider a thin horizontal layer of the atmosphere, of thickness dy, of area A, with pressure P on the bottom, with an average mass m per molecule, and nV molecules per unit volume, the magnitude of the difference of the pressure at the top and bottom of the layer is given by dP =

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An ideal gas is allowed to expand adiabatically until its volume increases by 50%. By approximately what factor is the pressure reduced? (γ = 5/3.)

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The root mean square speed of a gas molecule is greater than the average speed, because the former gives a greater weight to

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The average molecular translational kinetic energy of a molecule in an ideal gas is

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A container having a volume of 1.0 m3 holds 5.0 moles of helium gas at 50°C. If the helium behaves like an ideal gas, the total energy of the system is

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A container having a volume of 1.0 m3 holds 5.0 moles of helium gas at 50°C. If the helium behaves like an ideal gas, the average kinetic energy per molecule is

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The temperature of a quantity of an ideal gas is

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A molecule in a uniform ideal gas can collide with other molecules when their centers are equal to or less than

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A 50-gram sample of dry ice (solid CO2) is placed in a 4-liter container. The system is sealed and allowed to reach room temperature (20°C). By approximately how much does the pressure inside the container increase when the dry ice turns to gas? (Ignore the initial volume of the sample.)

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Which statement below is NOT an assumption made in the molecular model of an ideal gas?

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