Exam 4: Quantum Mechanics, Atomic Structure, Quantum Mechanics and Molecular Structure

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A MO orbital for a heteronuclear diatomic is given byA MO orbital for a heteronuclear diatomic is given by  If A is more electronegative than B then you would predict that If A is more electronegative than B then you would predict that

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A

Given that Zeff(2s) in Li is 1.26, estimate the energy of the 2s electron in Li in Rhydberg units.

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The wavefunction for the 2s orbital in hydrogen is given by The wavefunction for the 2s orbital in hydrogen is given by   At what radius is there a node? At what radius is there a node?

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Oxygen is paramagnetic and has a bond order of two. Which of the following represents the ground electronic state for oxygen?

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Which of the following combinations of atomic orbitals will result in a bonding molecular orbital for a homonuclear diatomic molecule when the z-axis is aligned with the nuclei of the bonded atom?

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Of the following angular components for the wave functions of one-electron atoms, which one(s) must correspond only to s type orbitals?

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What do you predict of the electron configuration of element 117?

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Rank from smallest to largest in terms of atom/ionic radii.

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The molecule HeH+ has an antibonding MO of the form The molecule HeH<sup>+</sup> has an antibonding MO of the form   For this you would expect For this you would expect

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