Exam 12: Liquids, Solids, and Intermolecular Forces

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How much heat is released when 105 g of steam at 100.0°C is cooled to ice at -15.0°C? The enthalpy of vaporization of water is 40.67 kJ/mol,the enthalpy of fusion for water is 6.01 kJ/mol,the molar heat capacity of liquid water is 75.4 J/(mol ∙ °C),and the molar heat capacity of ice is 36.4 J/(mol ∙ °C).

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C

Consider the phase diagram below.If the dashed line at 1 atm of pressure is followed from 100 to 500°C,what phase changes will occur (in order of increasing temperature)? Consider the phase diagram below.If the dashed line at 1 atm of pressure is followed from 100 to 500°C,what phase changes will occur (in order of increasing temperature)?

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D

The normal boiling point for H2Se is higher than the normal boiling point for H2S .This can be explained by

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B

The boiling point of water is

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Which of the following must be overcome during the boiling of acetonitrile,CH3CN? 1)dispersion forces 2)dipole-dipole forces 3)hydrogen bonds

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Define viscosity.

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How much energy must be removed from a 94.4 g sample of benzene (molar mass= 78.11 g/mol)at 322.0 K to solidify the sample and lower the temperature to 205.0 K? The following physical data may be useful. ΔHvap = 33.9 kJ/mol ΔHfus = 9.8 kJ/mol Cliq = 1.73 J/g°C Cgas = 1.06 J/g°C Csol = 1.51 J/g°C Tmelting = 279.0 K Tboiling = 353.0 K

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Sketch the phase diagram of benzene.Make sure to label the axes and the different phases of benzene.Use the physical data provided below. melting point = 279 K boiling point = 353 K Tc = 562 K Pc = 48.4 atm Triple Point = 0.05 atm,279 K

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The enthalpy change for converting 10.0 g of ice at -25.0°C to water at 80.0°C is ________ kJ.The specific heats of ice,water,and steam are 2.09 J/gK,4.18 J/gK,and 1.84 J/gK,respectively.For H2O,ΔHfus = 6.01 kJ/mol,and ΔHvap = 40.67 kJ/mol.

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Determine the vapor pressure (in torr)of a substance at 36°C,whose normal boiling point is 84°C and has a ΔHvap of 22.1 kJ/mol.

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Identify the characteristics of a liquid.

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The set of conditions at which point a phase boundary no longer exists is know as the

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Why does the temperature of a substance stay constant during a phase change such as vaporization?

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Describe sweating in humans.

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Choose the substance with the highest viscosity.

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Describe the differences in the meniscuses of water and mercury.

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The resistance of a liquid to flow is known as

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The normal boiling point of diethyl ether is 34.6°C.At a pressure of 1.3 atm,the boiling point

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Place the following compounds in order of increasing strength of intermolecular forces. CO2 H2 H2O

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Which is expected to have the largest dispersion forces?

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