Exam 18: Aqueous Ionic Equilibrium

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A 1.50 L buffer solution is 0.250 M in HF and 0.250 M in NaF.Calculate the pH of the solution after the addition of 0.0500 moles of solid NaOH.Assume no volume change upon the addition of base.The Ka for HF is 3.5 × 10-4.

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Gives what happens at low pH for aluminum hydroxide.

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You have a 0.850 M solution of Na2CrO4 at a given temperature.At what concentration will silver ions need to be added in order for a participate to form? The Ksp for Ag2CrO4 at this temperature is 2.00 × 10-12.

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The molar solubility of CuI is 2.26 × 10-6 M in pure water.Calculate the Ksp for CuI.

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Gives what happens at high pH for aluminum hydroxide.

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If the pKa of HCHO2 is 3.74 and the pH of an HCHO2/NaCHO2 solution is 3.11,which of the following is TRUE?

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A 100.0 mL sample of 0.20 M HF is titrated with 0.10 M KOH.Determine the pH of the solution before the addition of any KOH.The Ka of HF is 3.5 × 10-4.

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A 100.0 mL sample of 0.18 M HClO4 is titrated with 0.27 M LiOH.Determine the pH of the solution after the addition of 50.0 mL of LiOH.

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Sketch the titration curve for a diprotic acid.Make sure to label the equivalence point(s)and the relative amounts of base that were added to reach them.

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A sample contains Ba3(PO4)2, CdS,AgCl,NH4Cl,and ZnS.Identify the precipitate after the addition of 6 M HCl; H2S and 0.2 M HCl; OH- to a pH of 8; and (NH4)2HPO4 with NH3.

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Determine the molar solubility for Zn(OH)2 in pure water.Ksp for Zn(OH)2 is 3.00 × 10-17.

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What volume of 5.00 × 10-3 M HNO3 is needed to titrate 40.00 mL of 5.00 × 10-3 M Ca(OH)2 to the equivalence point?

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A 100.0 mL sample of 0.10 M Ca(OH)2 is titrated with 0.10 M HBr.Determine the pH of the solution after the addition of 300.0 mL HBr.

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Calculate the pH of a solution formed by mixing 525 mL of 0.50 M H2CO3 with 355 mL of 0.87 M NaHCO3.The Ka for H2CO3 is 4.3× 10-7.

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Identify the compound that is acid-insoluble.

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What is the hydronium ion concentration in a solution prepared by mixing 50.00 mL of 0.10 M HCN with 50.00 mL of What is the hydronium ion concentration in a solution prepared by mixing 50.00 mL of 0.10 M HCN with 50.00 mL of   NaCN? Assume that the volumes of the solutions are additive and that K<sub>a</sub> =  NaCN? Assume that the volumes of the solutions are additive and that Ka = What is the hydronium ion concentration in a solution prepared by mixing 50.00 mL of 0.10 M HCN with 50.00 mL of   NaCN? Assume that the volumes of the solutions are additive and that K<sub>a</sub> =

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Animals will lick up ethylene glycol (antifreeze)due to its sweet taste.The antidote for ethylene glycol poisoning is the administration of

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Which of the following solutions is a good buffer system?

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A 100.0 mL sample of 0.20 M HF is titrated with 0.10 M KOH.Determine the pH of the solution after the addition of 100.0 mL of KOH.The Ka of HF is 3.5 × 10-4.

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Match the following.
pH = pKa
3/4 of the way to second equivalence point of a diprotic acid/strong base titration
pH = 7
half-way to equivalence point of a weak acid/strong base titration
pH = pKa2
equivalence point of a weak acid/strong base titration
Correct Answer:
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pH = pKa
3/4 of the way to second equivalence point of a diprotic acid/strong base titration
pH = 7
half-way to equivalence point of a weak acid/strong base titration
pH = pKa2
equivalence point of a weak acid/strong base titration
pH > 7
equivalence point of a strong acid/strong base titration
pH < 7
equivalence point of a weak base/strong acid titration
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