Exam 1: Chemical Foundations

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Which of the following is NOT one of the ways RNA differs from DNA?

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C

The amount of free energy released when bonds are broken during a reaction is higher when the molecule has more electronegative atoms.

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You discover that you suffer from a deficiency in the amino acid tryptophan.At the pharmacy,you find both d-tryptophan and l-tryptophan supplements.Which do you purchase? Why?

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You should choose l-tryptophan.All amino acids can exist as one of two stereoisomers (d or l)because of asymmetry around the α carbon.Proteins consist of the l form of amino acids,and as these stereoisomers possess distinct biological properties and are not readily interconverted,you should choose the form that is normally utilized by cells.

What produces the dipole of a water molecule?

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Which of the following is a monosaccharide?

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Cysteine often plays an important role in stabilizing protein structure.Explain how this works.

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Adenosine is a:

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Which of the following is the BEST explanation for why vegetable oil is a liquid at room temperature while animal fats are solid?

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A 1-mL solution of 0.1 M NaOH is diluted to 1 L at 25°C.What is the pH of the resulting solution?

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The ultimate source of chemical energy for all cells is:

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In a biochemical reaction in which ΔH < 0 and ΔS > 0:

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In the reaction NAD⁺ + H⁺ + 2e−→ NADH,NAD⁺ becomes:

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Under what conditions is the ΔG for a reaction different from the ΔG°´?

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A nucleotide can vary in _____.

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What is the effect of an enzyme on the end equilibrium concentration of reactants and products?

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Which of the following is a noncovalent interaction?

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A reaction with a positive ΔG value can be made energetically favorable by increasing the:

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The enzyme alcohol dehydrogenase is capable of catalyzing the oxidation of a number of different substances,including ethanol,ethylene glycol,and methanol,to an aldehyde.The metabolic products of both ethylene glycol and methanol are highly toxic to humans.A standard medical treatment for prevention of ethylene glycol or methanol poisoning is the administration of a dose of ethanol.Why is this treatment effective?

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What is the major structural difference between starch and cellulose?

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Which of the following is the strongest interaction?

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