Exam 13: Physical Properties of Solutions

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What is the molality of a solution that is 3.68 % by mass calcium chloride?

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C

Which of the following gives the molarity of a 17.0 % by mass solution of sodium acetate, CH3COONa (molar mass = 82.0 g/mol)in water? The density of the solution is 1.09 g/mL.

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A 100.-mL sample of water is taken from the Pacific Ocean, and the water is allowed to evaporate. The salts that remain (mostly NaCl)have a mass of 3.85 g. Calculate the original concentration of NaCl, in g per liter, in the water sample.

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38.5 g/L

What is the percent CsCl by mass in a 0.711 M CsCl solution that has a density of 1.091 g/mL?

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Oxygen gas makes up 21 % of the atmosphere by volume. What is the solubility of O2(g)in water at 25°C if the atmospheric pressure is 741 mmHg? The Henry's law constant for oxygen gas at 25°C is 1.3 * 10-3 mol/L·atm.

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The solubility of CO2 gas in water

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What is the osmotic pressure of a solution prepared from 13.7 g of the electrolyte HCl and enough water to make 0.500 L of solution at 18°C?

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Which of the following aqueous solutions has the highest osmotic pressure at 25°C?

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Which of the following aqueous solutions has the highest boiling point? Kb for water is 0.52°C/m.

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A 9.50 % by mass solution of acetone (C3H6O)in water has a density of 0.9849 g/mL at 20°C. What is the molarity of this solution?

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The solubility of oxygen in water is about 4.5 * 10-2 g/L. The water portion of an adult's total blood supply is about 5 liters. How many grams of oxygen could dissolve in 5 liters of water?

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Which one of the following would be immiscible with water?

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Automobile radiators usually carry a sticker that indicates that they must contain an antifreeze solution for proper operation, winter or summer. Why should you not use ordinary water during the summer?

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The solubility of CO2 gas in water

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What is the freezing point of a solution that contains 10.0 g of glucose (C6H12O6)in 100. g of H2O? Kf for water is 1.86°C/m.

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Calculate the molality of a 20.0% by mass ammonium sulfate (NH4)2SO4 solution. The density of the solution is 1.117 g/mL.

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What volume of water should be added to 600. mL of ethanol in order to have a solution that boils at 95.0°C? (For ethanol, Kb = 1.22 °C/m, density = 0.789 g/cm3, boiling point = 78.4°C)

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The term "proof" is defined as twice the percent by volume of pure ethanol in solution. A solution that is 95% ethanol is 190 proof. What is the molarity of ethanol in a 92-proof ethanol/water solution? (Given: density of ethanol = 0.80 g/cm3; density of water = 1.0 g/cm3)

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The density of a 20.3 M CH3OH (methanol)solution is 0.858 g/mL. What is the molality of this solution? H2O is the solvent.

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What is the osmotic pressure of a 0.25 M solution of sucrose at 37°C? (R = 0.0821 L.atm/K.mol)

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