Exam 13: Physical Properties of Solutions

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What is the concentration of O2(g)in water at 25°C exposed to a partial pressure of oxygen of 325 mmHg? The Henry's law constant for oxygen gas at 25°C is 1.3 * 10-3 mol/L·atm.

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Maple syrup is mostly a solution of sucrose in water. Calculate the molality of the syrup if a sample freezes at -0.50°C, assuming the solute is pure sucrose. [For water, Kf is 1.86°C/m.]

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A solution is prepared by adding 40.3 g of Mg(NO3)2 to 127 g of water. Calculate the mole fraction and molality of magnesium nitrate in this solution.

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A solution that contains 55.0 g of ascorbic acid (VitaminC) in 250. g of water freezes at -2.34°C. Calculate the molar mass (in units of g/mol) of the solute. Kf of water is 1.86°C/m.

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During osmosis

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In which of the following solvents would you expect KBr to be most soluble?

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What is the boiling point of an aqueous solution of a nonelectrolyte that has an osmotic pressure of 10.50 atm at 25°C? Kb of water is 0.52°C/m. Assume the density of the solution is the same as that of pure water.

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Pure benzene, C6H6, freezes at 5.5° and boils at 80.1°C. What is the boiling point of a solution consisting of cyclohexane (C6H12)dissolved in benzene if the freezing point of this solution is 0.0°C? (For benzene, Kf = 5.12 °C/m, Kb = 2.53 °C/m; for cyclohexane, Kf = 20.0 °C/m, Kb = 2.79°C/m)

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When 12.1 g of the sugar sucrose (a nonelectrolyte)are dissolved in exactly 800 g of water, the solution has a freezing point of -0.082°C. What is the molar mass of sucrose? Kf of water is 1.86°C/m.

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What is the freezing point of an aqueous solution of a nonvolatile solute that has a boiling point of 102.5°C? For water Kf = 1.86°C/m and Kb = 0.52°C/m.

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Calculate the molality of a 15.0% by mass solution of MgCl2 in H2O. The density of this solution is 1.127 g/mL.

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The solubility of gases in water usually decreases with

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Explain the following, on the basis of osmosis or osmotic pressure: Drinking salt water actually dehydrates our tissues.

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Calculate the freezing point of a solution made from 22.0 g of octane (C8H18)dissolved in 148.0 g of benzene. Benzene freezes at 5.50°C and its Kf value is 5.12°C/m.

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The solubility of gases in water always decreases with increasing temperature.

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What is the osmotic pressure of a solution that contains 13.7 g of propyl alcohol (C3H7OH)dissolved in enough water to make 500. mL of solution at 27°C?

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When 20.0 grams of an unknown compound are dissolved in 500. grams of benzene, the freezing point of the resulting solution is 3.77°C. The freezing point of pure benzene is 5.444°C, and the Kf for benzene is 5.12°C/m. What is the molar mass of the unknown compound?

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When 24.0 g of glucose (a nonelectrolyte)are dissolved in 500. g of water, the solution has a freezing point of -0.47°C. What is the molar mass of glucose? Kf of water is 1.86°C/m.

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What is the molar mass of toluene if 0.85 g of toluene depresses the freezing point of 100. g of benzene by 0.47°C? Kf of benzene is 5.12°C/m.

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What volume of ethanol (density = 0.7893 g/cm3)should be added to 450. mL of water in order to have a solution that freezes at -15.0°C? (For water, Kf = 1.86 °C/m.)

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