Exam 13: Physical Properties of Solutions

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Some KCl is dissolved in water 25°C, where it completely dissociates. The vapor pressure of pure water at 25°C is 28.3 mmHg. Estimate the mass in grams of KCl needed per liter of pure water to reduce the vapor pressure of water at 25°C by 5%.

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Explain the following, on the basis of osmosis or osmotic pressure: In trees and plants water is drawn from the soil up into the branches and leaves.

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What is the molarity of a solution of 10 % by mass cadmium sulfate, CdSO4 (molar mass = 208.46 g/mol)by mass? The density of the solution is 1.10 g/mL.

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What mass of ethanol, C2H5OH a nonelectrolyte, must be added to 10.0 L of water to give a solution that freezes at -10.0°C? Assume the density of water is 1.0 g/mL. Kf of water is 1.86°C/m.

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Some KCl is dissolved in water 25°C, where it completely dissociates. The vapor pressure of pure water at 25°C is 28.3 mmHg. On the graph below, sketch the vapor pressure above the salt solution as a function of the mole fraction of H2O, assuming that Raoult's law is obeyed. Explain how you arrived at your graph. Some KCl is dissolved in water 25°C, where it completely dissociates. The vapor pressure of pure water at 25°C is 28.3 mmHg. On the graph below, sketch the vapor pressure above the salt solution as a function of the mole fraction of H<sub>2</sub>O, assuming that Raoult's law is obeyed. Explain how you arrived at your graph.

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What is the molality of a 0.142 M Na3PO4(aq)solution that has a density of 1.015 g/mL?

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What is the molarity of a solution that is 7.00 % by mass magnesium sulfate and has a density of 1.071 g/mL?

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Which response lists all the following pairs that are miscible liquids. Pair #1: octane (C8H18)and water Pair #2: acetic acid (CH3COOH)and water Pair #3: octane (C8H18)and carbon tetrachloride (CCl4)

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A solution is prepared by adding 6.24 g of benzene (C6H6, 78.11 g/mol)to 80.74 g of cyclohexane (C6H12, 84.16 g/mol). Calculate the mole fraction and molality of benzene in this solution.

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In the course of research, a chemist isolates a new compound with an empirical formula C3H3O2. Dissolving 2.51 g of the compound in 100. g of water produces a solution with a freezing point of -0.325°C. What is the molecular formula of the compound? (For water, Kf = 1.86°C/m.)

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Which of the following liquids would make a good solvent for iodine, I2?

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Calculate the molality of a solution containing 14.3 g of NaCl in 42.2 g of water.

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Explain the following, on the basis of osmosis or osmotic pressure: When sprinkled with sugar, a dish of sliced fruit will form its own juice.

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A 100. mL sample of water is taken from the Great Salt Lake, and the water is allowed to evaporate. The salts that remain (mostly NaCl)have a mass of 31.9 g Calculate the original concentration of NaCl, in g per liter, in each water sample.

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Calculate the approximate freezing point of a solution made from 21.0 g NaCl and 1.00 * 102 g of H2O. [Kf of water is 1.86°C/m.]

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A solution of carbon tetrachloride in benzene, C6H6, at 20°C has a total vapor pressure of 78.50 mmHg. (Assume that this solution is ideal.)The vapor pressure of pure benzene at this temperature is 74.61 mmHg and its density is 0.87865 g/cm3; the vapor pressure of pure carbon tetrachloride is 91.32 mmHg and its density is 1.5940 g/cm3. What percentage of the volume of this solution is due to carbon tetrachloride? (Hint: assume that you have 1.000 L of solution.)

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What is the molarity of a solution that is 5.50 % by mass oxalic acid (C2H2O4)and has a density of 1.0244 g/mL?

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A 15.00 % by mass solution of lactose (C12H22O11, 342.30 g/mol)in water has a density of 1.0602 g/mL at 20°C. What is the molarity of this solution?

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What is the mass percent CH3OH of a 0.256 m CH3OH(aq)solution?

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To interconvert the concentration units molality (m)and mass percent, you must also know the density of the solution.

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