Exam 8: Electron Delocalization, Resonance, and Aromaticity More About Molecular Orbital Theory

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Provide the major organic product. Provide the major organic product.

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When 1, 3-butadiene reacts with CH2 When 1, 3-butadiene reacts with CH<sub>2</sub> <sub> </sub>   CHCN, which of the terms below best describes the product mixture? CHCN, which of the terms below best describes the product mixture?

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The Diels-Alder reaction is a concerted reaction; this means that ________.

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Which of the following compounds is aromatic? Which of the following compounds is aromatic?

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What diene and dienophile should be used to synthesize the compound below and its enantiomer? What diene and dienophile should be used to synthesize the compound below and its enantiomer?

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Classify cyclopentadienyl cation as aromatic, antiaromatic, or nonaromatic. Assume planarity of the π network.

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In the addition of HBr to conjugated dienes, is the product which results from 1,2-addition or that which results from 1,4-addition typically the product of kinetic control?

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What is/are the product(s)from the following reaction? What is/are the product(s)from the following reaction?

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What diene and dienophile would react to give the product below? What diene and dienophile would react to give the product below?

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What compound results from the 1, 4-addition of one equivalent of HBr to 1, 3-butadiene?

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One of the following compounds is aromatic and the other is antiaromatic. Which is which? One of the following compounds is aromatic and the other is antiaromatic. Which is which?

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What is suggested by the fact that benzene's molar heat of hydrogenation is 36 kcal less than three times the molar heat of hydrogenation of cyclohexene?

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Draw the important resonance contributing forms for the structure shown below. Draw the important resonance contributing forms for the structure shown below.

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Give the major organic product for the reaction. Give the major organic product for the reaction.

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Identify the correctly drawn arrows.

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Mark the most electron-rich carbon atom in the compound below with an asterisk.

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Provide the structure of the major organic product in the following reaction. Provide the structure of the major organic product in the following reaction.

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Which of the following is/are the main product(s)of the following reaction? CH2 Which of the following is/are the main product(s)of the following reaction? CH<sub>2</sub><sub> </sub>   CH-CH   CH<sub>2 </sub> <sub> </sub>   ? CH-CH Which of the following is/are the main product(s)of the following reaction? CH<sub>2</sub><sub> </sub>   CH-CH   CH<sub>2 </sub> <sub> </sub>   ? CH2 Which of the following is/are the main product(s)of the following reaction? CH<sub>2</sub><sub> </sub>   CH-CH   CH<sub>2 </sub> <sub> </sub>   ? ?

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What is the kinetic product for the following reaction? What is the kinetic product for the following reaction?    What is the kinetic product for the following reaction?

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Is the following molecule aromatic? Explain. Is the following molecule aromatic? Explain.

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