Exam 8: Electron Delocalization, Resonance, and Aromaticity More About Molecular Orbital Theory

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Is the following molecule aromatic? Explain. Is the following molecule aromatic? Explain.

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Which of the structures below would be aromatic? Which of the structures below would be aromatic?

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Give the major organic product(s)for the reaction. Give the major organic product(s)for the reaction.

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Provide the major organic product of the following reaction. Provide the major organic product of the following reaction.

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In the molecular orbital representation of benzene, how many π molecular orbitals are present?

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Which of the following is the strongest acid? Which of the following is the strongest acid?

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List the criteria which compounds must meet in order to be considered aromatic.

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How many allylic hydrogen atoms are present in the following molecule? How many allylic hydrogen atoms are present in the following molecule?

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What diene and what dieneophile could be used to prepare the following? What diene and what dieneophile could be used to prepare the following?

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Draw the important resonance contributing forms for the structure shown below. Draw the important resonance contributing forms for the structure shown below.

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What diene and dienophile would react to give the product below? What diene and dienophile would react to give the product below?

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Among a series of isomeric trienes, the more negative the ΔH° of the hydrogenation reaction of a given triene, the ________ stable it is relative to the others in the isomeric series.

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Provide the structure of the major product which results from 1,2-addition of HBr to the diene shown below. Provide the structure of the major product which results from 1,2-addition of HBr to the diene shown below.

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What is the product of the following Diels-Alder reaction? What is the product of the following Diels-Alder reaction?

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Draw the important resonance structures of: Draw the important resonance structures of:

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In the acetate ion (CH3CO2-), which of the oxygen atoms bears a greater negative charge? Explain your answer.

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Is cyclooctatetraene a planar molecule? Explain.

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Which of the following is an isolated diene? Which of the following is an isolated diene?

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When 1, 3-cyclopentadiene reacts with the cis-isomer of NCCH=CHCN, the major product is ________.

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Which of the following is antiaromatic? Which of the following is antiaromatic?

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