Exam 17: Aqueous Ionic Equilibrium
Exam 1: Matter, measurement, and Problem Solving170 Questions
Exam 2: Atoms and Elements157 Questions
Exam 3: Molecules,compounds,and Chemical Equations175 Questions
Exam 4: Chemical Quantities and Aqueous Reactions239 Questions
Exam 5: Gases182 Questions
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Exam 7: The Quantum-Mechanical Model of the Atom134 Questions
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Exam 13: Solutions157 Questions
Exam 14: Chemical Kinetics154 Questions
Exam 15: Chemical Equilibrium141 Questions
Exam 16: Acids and Bases160 Questions
Exam 17: Aqueous Ionic Equilibrium187 Questions
Exam 18: Free Energy and Thermodynamics130 Questions
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Exam 21: Organic Chemistry104 Questions
Exam 22: Biochemistry68 Questions
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Exam 25: Transition Metals and Coordination Compounds73 Questions
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A solution is prepared by dissolving 0.23 mol of nitrous acid and 0.27 mol of sodium nitrite in water sufficient to yield 1.00 L of solution.The addition of 0.05 mol of HCl to this buffer solution causes the pH to drop slightly.The pH does not decrease drastically because the HCl reacts with the __________ present in the buffer solution.The Ka of nitrous acid is 1.36 × 10-3.
(Multiple Choice)
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Determine the molar solubility of CaSO4 in a solution containing 0.12 M K2SO4. Ksp (CaSO4)= 2.4 × 10-5.
(Multiple Choice)
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A solution contains 0.036 M Cu2+ and 0.044 M Fe2+.A solution containing sulfide ions is added to selectively precipitate one of the metal ions from solution.At what concentration of sulfide ion will a precipitate begin to form? What is the identity of the precipitate? Ksp(CuS)= 1.3 × 10-36,Ksp(FeS)= 6.3 × 10-18.
(Multiple Choice)
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A 1.50 L buffer solution is 0.250 M in HF and 0.250 M in NaF.Calculate the pH of the solution after the addition of 0.0500 moles of solid NaOH.Assume no volume change upon the addition of base.The Ka for HF is 3.5 × 10-4.
(Multiple Choice)
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How many milliliters of 0.120 M NaOH are required to titrate 50.0 mL of 0.0998 M butanoic acid to the equivalence point? The Ka of butanoic acid is 1.5 × 10-5.
(Multiple Choice)
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100.0 mL sample of 0.10 M NH3 is titrated with 0.10 M HNO3.Determine the pH of the solution before the addition of any HNO3.The Kb of NH3 is 1.8 × 10-5.
(Multiple Choice)
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A solution contains 0.021 M Cl⁻ and 0.017 M I⁻.A solution containing copper(I)ions is added to selectively precipitate one of the ions.At what concentration of copper(I)ion will a precipitate begin to form? What is the identity of the precipitate? Ksp(CuCl)= 1.0 × 10-6,Ksp(CuI)= 5.1 × 10-12.
(Multiple Choice)
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A solution containing AgNO3 is mixed with a solution of NaCl to form a solution that is 0.10 M in AgNO3 and 0.075 M in NaCl.What will happen once these solutions are mixed? Ksp (AgCl)= 1.77 × 10-10.
(Multiple Choice)
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A 1.50 L buffer solution is 0.250 M in HF and 0.250 M in NaF.Calculate the pH of the solution after the addition of 0.100 moles of solid NaOH.Assume no volume change upon the addition of base.The Ka for HF is 3.5 × 10-4.
(Multiple Choice)
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The largest change in pH for an effective buffer occurs when the base is how many times as concentrated as the acid?
(Multiple Choice)
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A 25.0-mL sample of 0.150 M butanoic acid is titrated with a 0.150 M NaOH solution.What is the pH after 13.3 mL of base is added? The Ka of butanoic acid is 1.5 × 10-5.
(Multiple Choice)
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What is the pH of a buffer solution that is 0.211 M in lactic acid and 0.111 M in sodium lactate? The Ka of lactic acid is 1.4 × 10-4.
(Multiple Choice)
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Calculate the pH of a solution formed by mixing 250.0 mL of 0.15 M NH4Cl with 200.0 mL of 0.12 M NH3.The Kb for NH3 is 1.8 × 10-5.
(Multiple Choice)
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What is the molar solubility of calcium fluoride (CaF2)in water? The solubility-product constant for CaF2 is 3.9 × 10-11 at 25°C.
(Multiple Choice)
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Calculate the pH of a buffer that is 0.020 M HF and 0.040 M NaF.The Ka for HF is 3.5 × 10-4.
(Multiple Choice)
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Calculate the pH of a buffer that is 0.032 M HF and 0.032 M NaF.The Ka for HF is 3.5 × 10-4.
(Multiple Choice)
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When a diprotic acid is titrated with a strong base,and the Ka1 and Ka2 are significantly different,then the pH vs.volume plot of the titration will have
(Multiple Choice)
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