Exam 17: Aqueous Ionic Equilibrium

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What is the pH of a solution prepared by mixing 50.00 mL of 0.10 M NH3 with 5.00 mL of 0.10 M NH4Cl? Assume that the volume of the solutions are additive and that Kb = 1.8 × 10-5 for NH3.

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A 1.00 L buffer solution is 0.250 M in HF and 0.250 M in NaF.Calculate the pH of the solution after the addition of 100.0 mL of 1.00 M HCl.The Ka for HF is 3.5 × 10-4.

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What is the molar solubility of Mg(OH)2 in a basic solution with a pH of 12.50? Ksp for Mg(OH)2 is 5.6 × 10-12.

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Determine the molar solubility of BaF2 in a solution containing 0.0750 M LiF. Ksp (BaF2)= 1.7 × 10-6.

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Determine the molar solubility for Pb3(PO4)2 in pure water.Ksp for Pb3(PO4)2 is 1.0 × 10-54.

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Calculate the pH of a solution formed by mixing 250.0 mL of 0.15 M NH4Cl with 100.0 mL of 0.20 M NH3.The Kb for NH3 is 1.8 × 10-5.

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Identify the indicator that can be used at the highest pH.

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A 100.0 mL sample of 0.10 M NH3 is titrated with 0.10 M HNO3.Determine the pH of the solution after the addition of 200.0 mL of HNO3.The Kb of NH3 is 1.8 × 10-5.

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A sample contains MgNH4(PO4)2, Sb2S3,KBr,Cr(OH)3,and PbCl2.Identify the precipitate after the addition of 6 M HCl.

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A 1.0 L buffer solution is 0.250 M HC2H3O2 and 0.060 M NaC2H3O2.Which of the following actions will destroy the buffer?

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What is the pH of a solution made by mixing 30.00 mL of 0.10 M HI with 40.00 mL of 0.10 M KOH? Assume that the volumes of the solutions are additive.

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Calculate the pH of a buffer that is 0.225 M HC2H3O2 and 0.162 M KC2H3O2.The Ka for HC2H3O2 is 1.8 × 10-5.

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A 100.0 mL sample of 0.10 M Ba(OH)2 is titrated with 0.10 M HCl.Determine the pH of the solution after the addition of 100.0 mL HCl.

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Calculate K. Cu(OH)2(aq)⇌ Cu2+(aq)+ 2 OH-(aq)Ksp = 1.6 × 10-19 Cu2+(aq)+ 4 NH3(aq)⇌ Cu(NH3)42+(aq)Kf = 1.7 × 1013 Cu(OH)2(aq)+ 4 NH3(aq)⇌ Cu(NH3)42+(aq)+ 2 OH-(aq)K = ?

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Identify the compound that is base-insoluble.

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A 1.00 L buffer solution is 0.250 M in HF and 0.250 M in LiF.Calculate the pH of the solution after the addition of 0.150 moles of solid LiOH.Assume no volume change upon the addition of base.The Ka for HF is 3.5 × 10-4.

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When titrating a weak monoprotic acid with NaOH at 25°C,the

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Determine the molar solubility of AgBr in a solution containing 0.150 M NaBr. Ksp (AgBr)= 7.7 × 10-13.

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A 110.0 mL sample of 0.20 M HF is titrated with 0.10 M CsOH.Determine the pH of the solution after the addition of 440.0 mL of CsOH.The Ka of HF is 3.5 × 10-4.

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0.10 M potassium chromate is slowly added to a solution containing 0.50 M AgNO3 and 0.50 M Ba(NO3)2.What is the Ag+ concentration when BaCrO4 just starts to precipitate? The Ksp for Ag2CrO4 and BaCrO4 are 1.1 × 10-12 and 1.2 × 10-10,respectively.

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