Exam 6: Isomerism 1: Conformational and Constitutional Isomers

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Which of the following has the least ring strain? Which of the following has the least ring strain?

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C

Which of the following types of isomer differs only by the rotation about single bonds?

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C

Clearly draw the most stable conformer of the following molecule in chair formation. Clearly draw the most stable conformer of the following molecule in chair formation.

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Would the cis or trans isomer be more stable for the following disubstituted cyclohexane? Explain. Would the cis or trans isomer be more stable for the following disubstituted cyclohexane? Explain.

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Which of the following Newman projections is least stable? Which of the following Newman projections is least stable?

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Conformational isomers differ by __________.

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Draw the dash-wedge structure that corresponds to the following Newman projection. Draw the dash-wedge structure that corresponds to the following Newman projection.

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A molecule has two rings,three double bonds,and two triple bonds.How many IHD units does this molecule have?

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Which of the following chair conformations is lowest in energy? Which of the following chair conformations is lowest in energy?

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How many of the following chair conformations have CH3 groups that are trans to each other? How many of the following chair conformations have CH<sub>3 </sub>groups that are trans to each other?

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Label each of the following molecules as cis or trans. Label each of the following molecules as cis or trans.

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Draw the Newman projection that corresponds to the following species. Draw the Newman projection that corresponds to the following species.

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Draw the most stable Newman projection for 1-bromo-2-chloroethane.

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Which of the following dash-wedge structures best represents the Newman projection below? Which of the following dash-wedge structures best represents the Newman projection below?

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Which substituents are anti to each other? Which substituents are anti to each other?

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Draw the following molecule after it undergoes a chair flip. Draw the following molecule after it undergoes a chair flip.

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Draw the dash-wedge structure that corresponds to the following Newman projection. Draw the dash-wedge structure that corresponds to the following Newman projection.

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Which of the following compounds has/have substituents cis to each other? Which of the following compounds has/have substituents cis to each other?

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Draw all alkyne-containing isomers of C5H8.

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Draw six constitutional isomers for C4H11N.

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