Exam 26: The Dielsalder Reaction and Other Pericyclic Reactions

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What is the major product of the following Diels-Alder reaction? Be sure to pay attention to regiochemistry. What is the major product of the following Diels-Alder reaction? Be sure to pay attention to regiochemistry.

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What is the product of the following reaction? What is the product of the following reaction?

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E

Which of the following can be used as the required diene in a Diels-Alder reaction? Which of the following can be used as the required diene in a Diels-Alder reaction?

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What is the major product of the following reaction? What is the major product of the following reaction?

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What is the expected product of the reaction below? What is the expected product of the reaction below?

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Show the diene and the dienophile required to synthesize the following molecule. Show the diene and the dienophile required to synthesize the following molecule.

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Supply the products and give the mechanism for the following retro Diels-Alder reaction. Supply the products and give the mechanism for the following retro Diels-Alder reaction.

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What reagents are needed to complete the following reaction? What reagents are needed to complete the following reaction?

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What reagent(s)will complete the following reaction? What reagent(s)will complete the following reaction?

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What is the major product of the following Diels-Alder reaction? Be sure to pay attention to regiochemistry. What is the major product of the following Diels-Alder reaction? Be sure to pay attention to regiochemistry.

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Show the product(s)of the following reaction. Show the product(s)of the following reaction.

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Which set of resonance structures is responsible for determining the regiochemistry of the Diels-Alder reaction between the following diene and dienophile? Which set of resonance structures is responsible for determining the regiochemistry of the Diels-Alder reaction between the following diene and dienophile?

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Circle the dienes that can participate in a Diels-Alder reaction with ethene. Circle the dienes that can participate in a Diels-Alder reaction with ethene.

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Which is true about the mechanism for a Diels-Alder reaction?

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What is the product of the following reaction? What is the product of the following reaction?

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Which of the following could be considered an endo product of a Diels-Alder reaction? Which of the following could be considered an endo product of a Diels-Alder reaction?

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What is the product of the following reaction? What is the product of the following reaction?

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Rank the following dienes in order of slowest to fastest rate of reaction with trans-2-butene. Rank the following dienes in order of slowest to fastest rate of reaction with trans-2-butene.

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Which of the following dienophiles would react fastest in a Diels-Alder reaction? Which of the following dienophiles would react fastest in a Diels-Alder reaction?

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What reagents are required to complete the following reaction? What reagents are required to complete the following reaction?

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