Exam 9: Nuclear Magnetic Resonance and Mass Spectrometry: Tools for Structure Determination
Exam 1: Carbon Compounds and Chemical Bonds134 Questions
Exam 2: Representative Carbon Compounds: Functional Groups, Intermolecular Forces, and Infrared Ir Spectroscopy114 Questions
Exam 3: An Introduction to Organic Reactions: Acids and Bases47 Questions
Exam 4: Alkanes: Nomenclature, Conformational Analysis, and an Introduction to Synthesis125 Questions
Exam 5: Stereochemistry: Chiral Molecules150 Questions
Exam 6: Ionic Reactions - Nucleophilic Substitution and Elimination Reactions of Alkyl Halides146 Questions
Exam 7: Alkenes and Alkynes I: Properties and Synthesis, Elimination Reactions of Alkyl Halides99 Questions
Exam 8: Alkenes and Alkynes Ii: Addition Reactions140 Questions
Exam 9: Nuclear Magnetic Resonance and Mass Spectrometry: Tools for Structure Determination94 Questions
Exam 10: Radical Reactions114 Questions
Exam 11: Alcohols and Ethers172 Questions
Exam 12: Alcohols From Carbonyl Compounds Oxidation-Reduction and Organometallic Compounds147 Questions
Exam 13: Conjugated Unsaturated Systems166 Questions
Exam 14: Aromatic Compounds151 Questions
Exam 15: Reactions of Aromatic Compounds173 Questions
Exam 16: Aldehydes and Ketones I Nucleophilic Addition to the Carbonyl Group165 Questions
Exam 17: Aldehydes and Ketones Ii Aldol Reactions131 Questions
Exam 18: Carboxylic Acids and Their Derivatives Nucleophilic Addition - Elimination at the Acyl Carbon124 Questions
Exam 19: Synthesis and Reactions of Beta-Dicarbonyl Compounds: More Chemistry of Enolate Ions131 Questions
Exam 20: Amines148 Questions
Exam 21: Phenols and Aryl Halides: Nucleophilic Aromatic Substitution87 Questions
Exam 22: Carbohydrates104 Questions
Exam 23: Lipids99 Questions
Exam 24: Amino Acids and Proteins94 Questions
Exam 25: Nucleic Acids and Protein Synthesis89 Questions
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Which one of the following best represents the predicted approximate chemical shift and coupling for the hydrogen(s)indicated with the arrow? 

(Multiple Choice)
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What is the structure of the compound in the following 1H-NMR spectrum with the molecular formula C5H11NO? In the 13C-NMR spectrum you notice that the farthest peak downfield has a chemical shift of 173 ppm.Relative integration is shown. 

(Multiple Choice)
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Which one of the following best represents the predicted approximate chemical shift and coupling for the hydrogen(s)indicated with the arrow? 

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A mass spectrometer sorts ions on the basis of their _______________.
(Short Answer)
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In electron impact mass spectrometry,a beam of high-energy electrons initially dislodges one electron from the compound being studied.This produces a positively charged ion called the ____________________.
(Short Answer)
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What is the structure of the compound in the following 1H-NMR spectrum with the molecular formula C8H14? Relative integration is shown. 

(Multiple Choice)
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Which one of the following best represents the predicted approximate chemical shift and coupling for the hydrogen(s)indicated with the arrow? 

(Multiple Choice)
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A compound with the molecular formula C8H9ClO gave the following 1H NMR spectrum: triplet, 3.7
Triplet, 4.2
Multiplet 7.1
There was no evidence of an -OH band in the IR spectrum.The most likely structure for the compound is:

(Multiple Choice)
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A compound with the molecular formula C8H9BrO gave the following 1H NMR spectrum: triplet, 1.4
Quartet, 3.9
Multiplet, 7.0 (4H)
There was no evidence of an -OH band in the IR spectrum.A possible structure for the compound is:

(Multiple Choice)
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What is the structure of the compound in the following 1H-NMR spectrum with the molecular formula C10H11N? Looking at the 13C-NMR you notice 10 distinct peaks,and the IR has a characteristic peak around 2250 cm-1.Relative integration is shown. 

(Multiple Choice)
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The 1H NMR spectrum of which of these compounds would consist of a triplet,singlet and quartet only?
(Multiple Choice)
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Predict the splitting pattern you would observe for the proton at C3 of 2,3-dimethyl-2-phenylbutane. 

(Multiple Choice)
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A compound C5H10O gave the following spectral data: 1H NMR spectrum IR spectrum
Doublet, 1.10 strong peak
Singlet, 2.10 near 1720 cm-1
Septet, 2.50
Which is a reasonable structure for the compound?

(Multiple Choice)
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A compound with the molecular formula C10H13Cl gave the following 1H NMR spectrum: singlet, 1.6
Singlet, 3.1
Multiplet, 7.2 (5H)
The most likely structure for the compound is:

(Multiple Choice)
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What is the structure of the compound in the following 1H-NMR spectrum with the molecular formula C10H12O2? Relative integration is shown. 

(Multiple Choice)
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How many signals will be recorded in the broadband proton-decoupled 13C spectrum of 4-chloro-1-ethylbenzene? 

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Consider the expected splitting of signal "b" in the 1H NMR spectrum of 1-methoxy-2-methylpropane,shown below.Presuming that Jab is sufficiently different from Jbc and that the instrument has sufficient resolving power,what is the theoretical multiplicity of signal "b"? 

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What can be determined from the relative abundance of the M + +1 peak?
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