Exam 5: Aromatic Compounds

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Instructions: Given the major organic product(s) of each of the following reactions. If no reaction is predicted, write "N.R." Write the product: Instructions: Given the major organic product(s) of each of the following reactions. If no reaction is predicted, write N.R. Write the product:

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Instructions: Provide the IUPAC name for each of the following compounds. IUPAC Name:

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  m-nitrotoluene m-nitrotoluene

What is the major organic product obtained from the following reaction? What is the major organic product obtained from the following reaction?

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C

Instructions: Consider the reaction below to answer the following question(s). Instructions: Consider the reaction below to answer the following question(s).   Refer to instructions. This reaction proceeds _____________ (faster or slower) than benzene. Refer to instructions. This reaction proceeds _____________ (faster or slower) than benzene.

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Which of the following sets of substituents are all o/p-directing in electrophilic aromatic substitution reactions?

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Instructions: Consider the reaction below to answer the following question(s). Instructions: Consider the reaction below to answer the following question(s).   Refer to instructions. Draw the structure of product  D. Refer to instructions. Draw the structure of product D.

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What is the IUPAC name of the following compound? What is the IUPAC name of the following compound?

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Draw the structure of m-fluoronitrobenzene.

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Draw the structure of 3,5-dimethylphenol.

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Instructions: Consider the Friedel-Crafts alkylation reaction below to answer the following questions: Instructions: Consider the Friedel-Crafts alkylation reaction below to answer the following questions:   What is the role of the AlCl<sub>3</sub> in the reaction? What is the role of the AlCl3 in the reaction?

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Which of the following compounds is aromatic?

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Consider the production of 1-bromo-4-nitrobenzene: Consider the production of 1-bromo-4-nitrobenzene:   a)	Explain why Pathway A for the production of 1-bromo-4-nitrobenzene produces a higher yield of the product.  	  b)	If reaction Pathway A is carried out at high temperatures, a trisubstituted product forms. Draw the structure of the product and explain why it forms. a) Explain why Pathway A for the production of 1-bromo-4-nitrobenzene produces a higher yield of the product. b) If reaction Pathway A is carried out at high temperatures, a trisubstituted product forms. Draw the structure of the product and explain why it forms.

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What is the IUPAC name of the following compound? What is the IUPAC name of the following compound?

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Instructions: Given the major organic product(s) of each of the following reactions. If no reaction is predicted, write "N.R." Write the product:

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Draw the structure of o-hydroxybenzoic acid.

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What is the correct assignment of the names of the following aromatic compounds? What is the correct assignment of the names of the following aromatic compounds?

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Instructions: Consider the reaction below to answer the following question(s). Instructions: Consider the reaction below to answer the following question(s).   Refer to instructions. The nucleophile in the reaction is indicated by letter _____. Refer to instructions. The nucleophile in the reaction is indicated by letter _____.

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Circle the compound(s) in the following set that will undergo both substitution and addition when treated with Br2. Circle the compound(s) in the following set that will undergo both substitution and addition when treated with Br<sub>2</sub>.

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Which of the following undergoes the most rapid acylation upon treatment with acetyl chloride and AlCl3?

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Instructions: Consider the reaction below to answer the following question(s). Instructions: Consider the reaction below to answer the following question(s).   Refer to instructions. The Lewis acid catalyst in the reaction is indicated by letter _____. Refer to instructions. The Lewis acid catalyst in the reaction is indicated by letter _____.

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